Glass

   

The materials definition of a glass is a uniform amorphous solid material, usually produced when a suitably viscous molten material cools very rapidly to below its glass transition temperature, thereby not giving enough time for a regular crystal lattice to form. A simple example is when table sugar is melted and cooled rapidly by dumping the liquid sugar onto a cold surface. The resulting solid is amorphous, not crystalline like the sugar was originally, which can be seen in its conchoidal fracture.

Look up glass in Wiktionary, the free dictionary.

The word glass comes from Latin glacies (ice) and corresponds to German Glas, M.E. glas, A.S. glaes. Germanic tribes used the word glaes to describe amber, recorded by Roman historians as glaesum. Anglo-Saxons used the word glaer for amber.

The term enamel is used to describe glass fused as a decorative or functional coating on metal.

The remainder of this article will be concerned with a specific type of glass—the silica-based glasses in common use as a building, container or decorative material.


In its pure form, glass is a transparent, relatively strong, hard-wearing, essentially inert, and biologically inactive material which can be formed with very smooth and impervious surfaces. These desirable properties lead to a great many uses of glass. Glass is, however, brittle and will break into sharp shards. These properties can be modified, or even changed entirely, with the addition of other compounds or heat treatment.

Common glass contains about 70% amorphous silicon dioxide (SiO2), which is the same chemical compound found in quartz, and its polycrystalline form, sand.

Properties and uses

Glass can be made transparent and flat, or into other shapes and colours as shown in this ball from the Verrerie of Brehat in Brittany.

One of the most obvious characteristics of ordinary glass is that it is transparent to visible light (not all glassy materials are). The transparency is due to an absence of electronic transition states in the range of visible light, and to the fact that such glass is homogeneous on all length scales greater than about a wavelength of visible light (inhomogeneities cause light to be scattered, breaking up any coherent image transmission). Ordinary glass does not allow light at a wavelength of lower than 400 nm, also known as ultraviolet light or UV, to pass. This is due to the addition of compounds such as soda ash (sodium carbonate).

Pure SiO2 glass (also called fused quartz) does not absorb UV light and is used for applications that require transparency in this region, although it is more expensive. This type of glass can be made so pure that hundreds of kilometres of glass are transparent at infrared wavelengths in fibre optic cables. Individual fibres are given an equally transparent core of SiO2/GeO2 glass, which has only slightly different optical properties (the germanium contributing to a higher index of refraction). Undersea cables have sections doped with erbium, which amplify transmitted signals by laser emission from within the glass itself.

Amorphous SiO2 is also used as a dielectric material in integrated circuits, due to the smooth and electrically neutral interface it forms with silicon.

Glasses used for making optical devices are commonly categorized using a six-digit glass code, or alternatively a letter-number code from the Schott Glass catalogue. For example, BK7 is a low-dispersion borosilicate crown glass, and SF10 is a high-dispersion dense flint glass. The glasses are arranged by composition, refractive index, and Abbe number.

Glass is sometimes created naturally from volcanic magma. This glass is called obsidian, and is usually black with impurities. Obsidian is a raw material for flint knappers, who have used it to make extremely sharp knives since the stone age. Collecting obsidian from national parks and some places may be prohibited by law, but the same toolmaking techniques can be applied to industrially-made glass.

Glass ingredients

Pure silica (SiO2) has a melting point of about 2000 °C (3600 °F), and while it can be made into glass for special applications (see fused quartz), two other substances are always added to common glass to simplify processing. One is soda (sodium carbonate Na2CO3), or potash, the equivalent potassium compound, which lowers the melting point to about 1000 °C (1800 °F). However, the soda makes the glass water-soluble, which is obviously undesirable, so lime (calcium oxide, CaO) is the third component, added to restore insolubility. The resulting glass contains about 70% silica and is called a soda-lime glass. Soda-lime glasses account for about 90% of manufactured glass.

As well as soda and lime, most common glass has other ingredients added to change its properties. Lead glass, such as lead crystal or flint glass, is more 'brilliant' because the increased refractive index causes noticeably more "sparkles", while boron may be added to change the thermal and electrical properties, as in Pyrex. Adding barium also increases the refractive index. Thorium oxide gives glass a high refractive index and low dispersion, and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern glasses. Large amounts of iron are used in glass that absorbs infrared energy, such as heat absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs UV wavelengths (biologically damaging ionizing radiation).

Glass as a polymer

An innovative way for making glass involves preparation by polymerization. Putting in additives that modify the properties of glass is problematic, because the high temperature of preparation destroys most of them. By polymerizing glass it is possible to embed active molecules, such as enzymes, to add a new level of functionality to the glass vessels. sol gel is a good example of glass prepared in this way.

Colours

Metallic additives in the glass mix can produce a variety of colours. Here cobalt has been added to produce a bluish coloured decorative glass. The inside of a blue glass cup.

Metals and metal oxides are added to glass during its manufacture to change its colour. Manganese can be added in small amounts to remove the green tint lent by iron, or in higher concentrations to give glass an amethyst colour. Like manganese, selenium can be used in small concentrations to decolorize glass, or in higher concentrations to impart a reddish colour. Small concentrations of cobalt (0.025 to 0.1%) yield blue glass. Tin oxide with antimony and arsenic oxides produce an opaque white glass, first used in Venice to produce an imitation porcelain. 2 to 3% of copper oxide produces a turquoise colour. Pure metallic copper produces a very dark red, opaque glass, which is sometimes used as a substitute for gold in the production of ruby-coloured glass. Nickel, depending on the concentration, produces blue, or violet, or even black glass. Adding titanium produces yellowish-brown glass. Metallic gold, in very small concentrations (around 0.001%), produces a rich ruby-coloured glass, while lower concentrations produces a less intense red, often marketed as "cranberry". Uranium (0.1 to 2%) can be added to give glass a fluorescent yellow or green colour. Uranium glass is typically not radioactive enough to be dangerous, but if ground into a powder, such as by polishing with sandpaper, and inhaled, it can be carcinogenic. Silver compounds (notably silver nitrate) can produce a range of colors from orange-red to yellow. The way the glass is heated and cooled can significantly affect the colors produced by these compounds. The chemistry involved is complex and not well understood. New coloured glasses are frequently discovered.

History of glass

Naturally occurring glass, such as obsidian, has been used since the stone age. Glass making instructions were first documented in Egypt around 1500 BC, when glass was used as a glaze for pottery and other items. In the first century BC the technique of blowing glass was developed and what had once been an extremely rare and valuable item became much more common.

During the Roman Empire many forms of glass were created, usually for vases and bottles. Glass was made from sand, plant ash and lime. The earliest use of glass was as a coloured, opaque, or transparent glaze applied to ceramics before they were fired. Small pieces of coloured glass were considered valuable and often rivalled precious gems as jewellery items. As time passed, it was discovered (most likely by a potter) that if glass is heated until it becomes semi-liquid, it can be shaped and left to cool in a new, solid, independently standing shape.

In the first century BC, somewhere at the eastern end of the Mediterranean, a new invention caused a true revolution in the glass industry. This was the discovery of glassblowing, both free-blowing and mould-blowing.

The colour of "natural glass" is green to bluish green. This colour is caused by the varying amounts of naturally occurring iron impurities in the sand. Common glass today usually has a slight green or blue tint, arising from these same impurities. Glassmakers learned to make coloured glass by adding metallic compounds and mineral oxides to produce brilliant hues of red, green, and blue - the colours of gemstones. When gem-cutters learned to cut glass, they found clear glass was an excellent refractor of light, the popularity of cut clear glass soared, that of coloured glass diminished.

Glass objects from the 7th and 8th centuries have been found on the island of Torcello near Venice. These form an important link between Roman times and the later importance of that city in the production of the material. About 1000 AD, an important technical breakthrough was made in Northern Europe when soda glass was replaced by glass made from a much more readily available material: potash obtained from wood ashes. From this point on, northern glass differed significantly from that made in the Mediterranean area, where soda remained in common use.

The 11th century saw the emergence, in Germany, of new ways of making sheet glass by blowing spheres, swinging these out to form cylinders, cutting these while still hot, and then flattening the sheets. This technique was perfected in 13th century Venice.

Until the 12th century, stained glass (i.e., glass with some colouring impurities, usually metals) was not widely used.

The centre for glass making from the 14th century was Venice, which developed many new techniques and became the centre of a lucrative export trade in dinner ware, mirrors, and other luxury items. Eventually some of the Venetian glass workers moved to other areas of northern Europe and glass making spread with them.

The Crown glass process was used up to the mid-1800s. In this process, the glassblower would spin around 9 lb (4 kg) of molten glass at the end of a rod until it flattened into a disk approximately 5 ft (1.5 m) in diameter. The disk would then be cut into panes. Venetian glass was highly prized between the 10th and 14th centuries as they managed to keep the process secret. Around 1688, a process for casting glass was developed, which led to its becoming a much more commonly used material. The invention of the glass pressing machine in 1827 allowed the mass production of inexpensive glass articles.

The cylinder method of creating flat glass was first used in the United States of America by William J. Blenko in the 1920s.

Art is sometimes etched into glass via acid or other caustic substance (causing the image to be eaten into the glass). Traditionally this was done by a trained artisan after the glass was blown or cast. In the 1920s a new mould-etch process was invented, in which art was etched directly into the mould, so that each cast piece emerged from the mold with the image already on the surface of the glass. This reduced manufacturing costs and, combined with a wider use of coloured glass, led to cheap popular glassware in the 1930s, which later became known as Depression glass.

See also: Broad sheet, Blown plate, Polished plate, Cylinder blown sheet, Machine drawn cylinder sheet

Glass tools

Since glass is strong and unreactive, it is a very useful material. Many household objects are made of glass. Drinking glasses, bowls, and bottles are often made of glass, as are light bulbs, mirrors, the picture tubes of computer monitors and televisions, and windows. In laboratories doing research in chemistry, biology, physics and many other fields, flasks, test tubes, lenses and other laboratory equipment are often made of glass. For these applications, borosilicate glass (such as Pyrex) is usually used for its strength and low coefficient of thermal expansion, which gives greater resistance to thermal shock and allows for greater accuracy in laboratory measurements when heating and cooling experiments. For the most demanding applications, quartz glass is used, although it is very difficult to work. Most such glass is mass-produced using various industrial processes, but most large laboratories need so much custom glassware that they keep a glassblower on staff. Volcanic glasses, such as obsidian, have long been used to make stone tools, and flint knapping techniques can easily be adapted to mass-produced glass.

Glass art

Glass sculpture by Dale Chihuly at an exhibition in Kew Gardens, London, England. The piece is 13 feet (4 metres) high

Even with the availability of common glassware, hand blown or lampworked glassware remains popular for its artistry. Some artists in glass include Lino Tagliapietra, Sidney Waugh, Rene Lalique, Dale Chihuly, and Louis Comfort Tiffany, who were responsible for extraordinary glass objects. The term "crystal glass", derived from rock crystal, has come to denote high-grade colourless glass, often containing lead, and is sometimes applied to any fine hand-blown glass.

There are many techniques for creating fine glass art; each is suitable for certain kinds of object and unsuitable for others. Someone who works with hot glass is called a glassblower or lampworker, and these techniques are how most fine glassware is created. Glass that is manipulated in a kiln is called warm glass, and traditional stained glass work is commonly called cold glass work. Glass can also be cut with a diamond saw, and polished to give gleaming facets.

Hand-blown glass beads and pendants illustrate some of the myriad colors and shapes of glass art. The Canadian Nickel is for scale.

Objects made out of glass include vessels (bowls, vases, and other containers), paperweights, marbles, beads, smoking pipes, bongs, and sculptures. Colored glass is often used, and sometimes the glass is painted, although many glassblowers consider this crude. A significant exception is the collection of pieces by the Blaschkas.

The Harvard Museum of Natural History has a collection of extremely detailed models of flowers made of painted glass. These were lampworked by Leopold Blaschka and his son Rudolph, who never revealed the method he used to make them. The Blaschka Glass Flowers are still an inspiration to glassblowers today. See the Harvard Museum of Natural History's page on the exhibit for further information.

Stained glass is an art form with a long history; many churches have beautiful stained-glass windows.

Glass in buildings

Main articles: Architectural Glass and Glazing

Glass has been used in buildings since the 11th century. Typical uses for glass in buildings include as a transparent material for windows in the building envelope, as internal glazed partitions and as architectural features.

Glass in buildings can be of a safety type, including wired, toughened and laminated glasses.

Glass fibre insulation is common in roofs and walls. Foamed glass, made from waste glass, can be used as lightweight, closed-cell insulation.

Several methods of producing glass for applications have been developed, including:

These glass types can be further utilised by the following processes:

See also Window.

Glass as a liquid

One common misconception is that glass is a super-cooled liquid of practically infinite viscosity when at room temperature. Supporting evidence that is often offered is that old windows are often thicker at the bottom than at the top. It is then assumed that the glass was once uniform, but has flowed to its new shape.

The likely source of this belief is that when panes of glass were commonly made by glassblowers, the technique that was used was to spin molten glass so as to create a round, mostly flat and even plate (the Crown glass process, described above). This plate was then cut to fit a window. The pieces were not, however, absolutely flat; the edges of the disk would be thicker because of centripetal forces. When actually installed in a window frame, the glass would be placed thicker side down for the sake of stability and visual sparkle. Occasionally such glass has been found thinner side down, as would be caused by carelessness at the time of installation.

Note that pitch, another seemingly-solid material, is in fact a highly viscous liquid, 100 billion times as viscous as water. This property can be seen in the University of Queensland's pitch drop experiment, where each drop has taken approximately 10 years to fall into the beaker.


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This property can be seen in the University of Queensland's pitch drop experiment, where each drop has taken approximately 10 years to fall into the beaker. For example, gold is quite common in Turkey but considered a most valuable gift in Sicily. Note that pitch, another seemingly-solid material, is in fact a highly viscous liquid, 100 billion times as viscous as water. The symbolic value of gold varies wildly around the world, even within geographic regions. Occasionally such glass has been found thinner side down, as would be caused by carelessness at the time of installation. In Orthodox Christianity, the wedded couple is adorned with a golden crown during the ceremony, an amalgamation of symbolic rites. When actually installed in a window frame, the glass would be placed thicker side down for the sake of stability and visual sparkle. Wedding rings are traditionally made of gold; since it is long-lasting and unaffected by the passage of time, it is considered a suitable material for everyday wear as well as a metaphor for the relationship.

The pieces were not, however, absolutely flat; the edges of the disk would be thicker because of centripetal forces. Medieval kings were inaugurated under the signs of sacred oil and a golden crown, the latter symbolizing the eternal shining light of heaven and thus a Christian king's divinely inspired authority. This plate was then cut to fit a window. Winners of races and prizes are usually awarded the gold medal (such as the Olympic Games and the Nobel Prize), while many award statues are depicted in gold (such as the Academy Awards, the Emmy Awards and the British Academy Film Awards). The likely source of this belief is that when panes of glass were commonly made by glassblowers, the technique that was used was to spin molten glass so as to create a round, mostly flat and even plate (the Crown glass process, described above). Great human achievements are frequently rewarded with gold, in the form of medals and decorations. It is then assumed that the glass was once uniform, but has flowed to its new shape. Gold is associated with notable anniversaries, particularly in a 50 year cycle, such as a golden wedding anniversary, golden jubilee, etc.

Supporting evidence that is often offered is that old windows are often thicker at the bottom than at the top. On the other hand, eminent orators such as John Chrysostom were said to have a mouth of gold with a silver tongue. One common misconception is that glass is a super-cooled liquid of practically infinite viscosity when at room temperature. American Indians of the Sioux tribe called it "The yellow metal that makes the white man crazy". See also Window. In Communist propaganda, the golden pocket watch and its fastening golden chain were the characteristic accessories of the class enemy, the bourgeois and the industrial tycoons. These glass types can be further utilised by the following processes:. The Golden Calf is a widely-recognised symbol of idolatry and revolt against God.

Several methods of producing glass for applications have been developed, including:. Gold has been associated with the extremities of utmost evil and great sanctity throughout history. Foamed glass, made from waste glass, can be used as lightweight, closed-cell insulation. Gold used in dentistry is widely regarded as the safest form of restorative material, as well as the most successful. Glass fibre insulation is common in roofs and walls. Liver and kidney damage has, however, been reported for up to 50% of arthritis patients treated with gold-containing drugs. Glass in buildings can be of a safety type, including wired, toughened and laminated glasses. The human body does not absorb gold very well, thus compounds of gold are not normally very toxic.

Typical uses for glass in buildings include as a transparent material for windows in the building envelope, as internal glazed partitions and as architectural features. There is only one stable isotope of gold, and 18 radioisotopes with Au-195 being the most stable with a half-life of 186 days. Glass has been used in buildings since the 11th century. Gold also forms:. Main articles: Architectural Glass and Glazing. Such compounds containing the Au- anion are called aurides and include caesium auride, CsAu, rubidium auride, RbAu, and tetramethylammonium auride, (CH3)4N+ Au-. Stained glass is an art form with a long history; many churches have beautiful stained-glass windows. Gold also can under extreme conditions form a +5 state with fluorine (gold pentafluoride, AuF5), as well as (unusually for a metal), a -1 state.

See the Harvard Museum of Natural History's page on the exhibit for further information. Gold compounds can be aurous (univalent, +1) or auric (trivalent, +3). The Blaschka Glass Flowers are still an inspiration to glassblowers today. Although gold is a noble metal, it can form many compounds, auric chloride (AuCl3) and chlorauric acid (HAuCl4) being the most common. These were lampworked by Leopold Blaschka and his son Rudolph, who never revealed the method he used to make them. Roosevelt expropriated gold by Executive Order 6102, and President Richard Nixon closed the gold window by which foreign countries could exchange American dollars for gold at a fixed rate. The Harvard Museum of Natural History has a collection of extremely detailed models of flowers made of painted glass. President Franklin D.

A significant exception is the collection of pieces by the Blaschkas. Within the United States, the private possession of gold except as jewelry and coin collecting was banned between 1933 and 1975. Colored glass is often used, and sometimes the glass is painted, although many glassblowers consider this crude. Because of its use as a reserve store of value, the possession of gold is sometimes restricted or banned. Objects made out of glass include vessels (bowls, vases, and other containers), paperweights, marbles, beads, smoking pipes, bongs, and sculptures. Prices have risen to the $570/oz ($18,300/kg) mark in early 2006 [3]. Glass can also be cut with a diamond saw, and polished to give gleaming facets. Since 1968 the price of gold on the open market has ranged widely, with a record high of $850/oz ($27,300/kg) on 21 January 1980, to a low of $252.90/oz ($8,131/kg) on 21 June 1999 (London Fixing).

Glass that is manipulated in a kiln is called warm glass, and traditional stained glass work is commonly called cold glass work. Federal Reserve Bank, in New York. Someone who works with hot glass is called a glassblower or lampworker, and these techniques are how most fine glassware is created. The largest gold depository in the world is that of the U.S. There are many techniques for creating fine glass art; each is suitable for certain kinds of object and unsuitable for others. Central banks still hold historical gold reserves as a store of value although the level has generally been declining. The term "crystal glass", derived from rock crystal, has come to denote high-grade colourless glass, often containing lead, and is sometimes applied to any fine hand-blown glass. On March 17, 1968, economic circumstances caused the collapse of the gold pool, and a two-tiered pricing scheme was established whereby gold was still used to settle international accounts at the old $35.00 per troy ounce ($1.13/g) but the price of gold on the private market was allowed to fluctuate; this two-tiered pricing system was abandoned in 1975 when the price of gold was left to find its free-market level.

Some artists in glass include Lino Tagliapietra, Sidney Waugh, Rene Lalique, Dale Chihuly, and Louis Comfort Tiffany, who were responsible for extraordinary glass objects. By 1961 it was becoming hard to maintain this price, and a pool of US and European banks began to act together to defend the price against market forces. Even with the availability of common glassware, hand blown or lampworked glassware remains popular for its artistry. For a long period the United States government set the price of gold at $20.67 per troy ounce ($664.56/kg) but in 1934 the price of gold was set at $35.00 per troy ounce ($1125.27/kg). Volcanic glasses, such as obsidian, have long been used to make stone tools, and flint knapping techniques can easily be adapted to mass-produced glass. As part of this system, governments and central banks attempted to control the price of gold by setting values at which they would exchange it for currency. Most such glass is mass-produced using various industrial processes, but most large laboratories need so much custom glassware that they keep a glassblower on staff. Historically gold was used to back currency in an economic system known as the gold standard in which one unit of currency was equivalent to a certain weight of gold.

For the most demanding applications, quartz glass is used, although it is very difficult to work. The price of gold is determined on the open market, but a procedure known as the Gold Fixing in London, originating in 1919, provides a twice-daily benchmark figure to the industry. For these applications, borosilicate glass (such as Pyrex) is usually used for its strength and low coefficient of thermal expansion, which gives greater resistance to thermal shock and allows for greater accuracy in laboratory measurements when heating and cooling experiments. The purity of a gold bar can also be expressed as a decimal figure ranging from 0 to 1, known as the millesimal fineness, such as 0.995. In laboratories doing research in chemistry, biology, physics and many other fields, flasks, test tubes, lenses and other laboratory equipment are often made of glass. When it is alloyed with other metals the term carat or karat is used to indicate the amount of gold present, with 24 carats being pure gold and lower ratings proportionally less. Drinking glasses, bowls, and bottles are often made of glass, as are light bulbs, mirrors, the picture tubes of computer monitors and televisions, and windows. Like other precious metals, gold is measured by troy weight and by grams.

Many household objects are made of glass. No commercially viable mechanism for performing gold extraction from sea water has yet been identified. Since glass is strong and unreactive, it is a very useful material. The effort produced little gold and cost the German government far more than the commercial value of the gold recovered. See also: Broad sheet, Blown plate, Polished plate, Cylinder blown sheet, Machine drawn cylinder sheet. Unfortunately, his assessment of the concentration of gold in sea water was unduly high, probably due to sample contamination. This reduced manufacturing costs and, combined with a wider use of coloured glass, led to cheap popular glassware in the 1930s, which later became known as Depression glass. Fritz Haber (the German inventor of the Haber process) attempted commercial extraction of gold from sea water in an effort to help pay Germany's reparations following the First World War.

In the 1920s a new mould-etch process was invented, in which art was etched directly into the mould, so that each cast piece emerged from the mold with the image already on the surface of the glass. The world's oceans hold a vast amount of gold, but in very low concentrations (perhaps 1-2 parts per billion). Traditionally this was done by a trained artisan after the glass was blown or cast. The possibility of cheap man-made gold would have unforeseen economic and political consequences. Art is sometimes etched into glass via acid or other caustic substance (causing the image to be eaten into the glass). No economically feasible method to manufacture gold artificially has been found and published yet. Blenko in the 1920s. However, it is possible to obtain infinitesimally small amounts of gold by artificial nuclear transformations in particle accelerators The gold isotopes produced would likely be radioactive.

The cylinder method of creating flat glass was first used in the United States of America by William J. Modern science has since proven the impossibility of making gold from other elements via chemical reactions. The invention of the glass pressing machine in 1827 allowed the mass production of inexpensive glass articles. porcelain), while searching in vain for the philosopher's stone, which was supposed to turn mercury into gold. Around 1688, a process for casting glass was developed, which led to its becoming a much more commonly used material. Scientists, kings and charlatans obsessed with the secret art of alchemy accidentally invented practically useful materials (e.g. Venetian glass was highly prized between the 10th and 14th centuries as they managed to keep the process secret. The idea of producing gold out of lesser metals or other cheap substances has fascinated people throughout the centuries.

The disk would then be cut into panes. Other methods of assaying and purifying smaller amounts of gold include parting and inquartation as well as cuppelation, or refining methods based on the dissolution of gold in aqua regia. In this process, the glassblower would spin around 9 lb (4 kg) of molten glass at the end of a rod until it flattened into a disk approximately 5 ft (1.5 m) in diameter. After initial production, gold is often subsequently refined industrially by the Wohlwill process or the Miller process. The Crown glass process was used up to the mid-1800s. In South America, the controversial project Pascua Lama aims at exploitation of rich fields in the high mountains of Atacama, at the border between Chile and Argentina. Eventually some of the Venetian glass workers moved to other areas of northern Europe and glass making spread with them. Kolar Gold Fields in India is another example of a city being built on the greatest gold deposits in India.

The centre for glass making from the 14th century was Venice, which developed many new techniques and became the centre of a lucrative export trade in dinner ware, mirrors, and other luxury items. Siberian regions of the USSR also used to be significant in the global gold mining industry. Until the 12th century, stained glass (i.e., glass with some colouring impurities, usually metals) was not widely used. Mines in South Dakota and Nevada supply two-thirds of gold used in the United States. This technique was perfected in 13th century Venice. Other major producers are Canada, United States and Western Australia. The 11th century saw the emergence, in Germany, of new ways of making sheet glass by blowing spheres, swinging these out to form cylinders, cutting these while still hot, and then flattening the sheets. The Second Boer War of 1899–1901 between the British Empire and the white Boers was at least partly over the rights of miners and possession of the gold wealth in South Africa.

From this point on, northern glass differed significantly from that made in the Mediterranean area, where soda remained in common use. Gold fields in the Orange Free State and the Transvaal are deep and require the world's deepest mines. About 1000 AD, an important technical breakthrough was made in Northern Europe when soda glass was replaced by glass made from a much more readily available material: potash obtained from wood ashes. The city of Johannesburg was built atop the world's greatest gold finds. These form an important link between Roman times and the later importance of that city in the production of the material. This decline was due to the increasing difficulty of extraction and changing economic factors affecting the industry in South Africa. Glass objects from the 7th and 8th centuries have been found on the island of Torcello near Venice. Production in 1970 accounted for 79% of the world supply, producing about 1,000 tonnes, however production in 2004 was 342 tonnes.

When gem-cutters learned to cut glass, they found clear glass was an excellent refractor of light, the popularity of cut clear glass soared, that of coloured glass diminished. Since the 1880s South Africa has been the source for a large proportion of the world's gold supply. Glassmakers learned to make coloured glass by adding metallic compounds and mineral oxides to produce brilliant hues of red, green, and blue - the colours of gemstones. It is claimed, that all the gold that has been mined throughout the history of mankind could be incorporated in a solid ball with a diameter of 27 metres. Common glass today usually has a slight green or blue tint, arising from these same impurities. Ore grades of 30 g/1000 kg (30 ppm) are usually needed before gold is visible to the naked eye, therefore in most gold mines you will not see any gold. This colour is caused by the varying amounts of naturally occurring iron impurities in the sand. Economic gold extraction can be achieved from ore grades as little as 0.5 g/1000 kg (0.5 ppm) on average in large easily mined deposits, typical ore grades in open-pit mines are 1–5 g/1000 kg (1-5 ppm), ore grades in underground or hard rock mines are usually at least 3 g/1000 kg (3 ppm) on average.

The colour of "natural glass" is green to bluish green. Gold occurs in sea water at 0.1 to 2 mg/t (0.1 to 2 ppb by weight) depending on sample location. This was the discovery of glassblowing, both free-blowing and mould-blowing. Another important ore type is in sedimentary black shale and limestone deposits containing finely disseminated gold and other platinum group metals. In the first century BC, somewhere at the eastern end of the Mediterranean, a new invention caused a true revolution in the glass industry. In all these deposits the gold is in its native form. As time passed, it was discovered (most likely by a potter) that if glass is heated until it becomes semi-liquid, it can be shaped and left to cool in a new, solid, independently standing shape. Primary deposits can be weathered and eroded, with most of the gold being transported into stream beds where it congregates with other heavy minerals to form placer deposits.

Small pieces of coloured glass were considered valuable and often rivalled precious gems as jewellery items. There are several primary deposit types, common ones are termed reef or vein. The earliest use of glass was as a coloured, opaque, or transparent glaze applied to ceramics before they were fired. A deposit usually needs some form of secondary enrichment to form an economically viable ore deposit: either chemical or physical processes like erosion or solution or more generally metamorphism, which concentrates the gold in sulfide minerals or quartz. Glass was made from sand, plant ash and lime. The primary source of gold is usually igneous rocks or surface concentrations. During the Roman Empire many forms of glass were created, usually for vases and bottles. Hydrothermal ore deposits of gold occur in metamorphic rocks and igneous rocks; alluvial deposits and placer deposits originate from these sources.

In the first century BC the technique of blowing glass was developed and what had once been an extremely rare and valuable item became much more common. Gold is widely distributed in the Earth's crust at a background level of 0.03 g/1000 kg (0.03 ppm by weight). Glass making instructions were first documented in Egypt around 1500 BC, when glass was used as a glaze for pottery and other items. Rarer mineral associations are petzite, calaverite, sylvanite, muthmannite, nagyagite and krennerite. Naturally occurring glass, such as obsidian, has been used since the stone age. The most common sulfide associations are pyrite, chalcopyrite, galena, sphalerite, arsenopyrite, stibnite and pyrrhotite. New coloured glasses are frequently discovered. Common gold associations are quartz often as veins and sulfide minerals.

The chemistry involved is complex and not well understood. These grains occur between mineral grain boundaries or as inclusions within minerals. The way the glass is heated and cooled can significantly affect the colors produced by these compounds. Occasionally large accumulations of native gold (also known as nuggets) occur but usually gold occurs as minute grains. Silver compounds (notably silver nitrate) can produce a range of colors from orange-red to yellow. Due to its relative chemical inertness gold is usually found as the native metal or alloy. Uranium glass is typically not radioactive enough to be dangerous, but if ground into a powder, such as by polishing with sandpaper, and inhaled, it can be carcinogenic. Because of its historically high value, much of the gold mined throughout history is still in circulation in one form or another.

Uranium (0.1 to 2%) can be added to give glass a fluorescent yellow or green colour. During the 19th century, gold rushes occurred whenever large gold deposits were discovered, including the California, Colorado, Otago, Australia, Witwatersrand, Black Hills, and Klondike gold rushes. Metallic gold, in very small concentrations (around 0.001%), produces a rich ruby-coloured glass, while lower concentrations produces a less intense red, often marketed as "cranberry". For modern attempts to produce artificial gold, see gold synthesis. Adding titanium produces yellowish-brown glass. Their symbol for gold was the circle with a point at its center (☉), which was also the astrological symbol, the Egyptian hieroglyph and the ancient Chinese character for the Sun (now 日). Nickel, depending on the concentration, produces blue, or violet, or even black glass. Although they never succeeded in this attempt, the alchemists promoted an interest in what can be done with substances, and this laid a foundation for today's chemistry.

Pure metallic copper produces a very dark red, opaque glass, which is sometimes used as a substitute for gold in the production of ruby-coloured glass. The primary goal of the alchemists was to produce gold from other substances, such as lead — presumably by the interaction with a mythical substance called the philosopher's stone. 2 to 3% of copper oxide produces a turquoise colour. Gold in antiquity was relatively easy to obtain geologically; however, 75% of all gold ever produced has been extracted since 1910.[2] It has been estimated that all the gold in the world that has ever been refined would form a single cube 20 m (66 ft) a side. Tin oxide with antimony and arsenic oxides produce an opaque white glass, first used in Venice to produce an imitation porcelain. Gold has been used as a symbol for purity, value, royalty, and particularly roles that combine these properties (see gold album). Small concentrations of cobalt (0.025 to 0.1%) yield blue glass. Gold has long been considered one of the most precious metals, and its value has been used as the standard for many currencies (known as the gold standard) in history.

Like manganese, selenium can be used in small concentrations to decolorize glass, or in higher concentrations to impart a reddish colour. The European exploration of the Americas was fueled in no small part by reports of the gold ornaments displayed in great profusion by Native American peoples, especially in Central America, Peru, and Colombia. Manganese can be added in small amounts to remove the green tint lent by iron, or in higher concentrations to give glass an amethyst colour. Exploitation is said to date from the time of Midas, and this gold was important in the establishment of what is probably the world's earliest coinage in Lydia between 643 and 630 BC. Metals and metal oxides are added to glass during its manufacture to change its colour. The south-east corner of the Black Sea was famed for its gold. sol gel is a good example of glass prepared in this way. Gold is also mentioned several times in the Old Testament.

By polymerizing glass it is possible to embed active molecules, such as enzymes, to add a new level of functionality to the glass vessels. Egypt and Nubia had the resources to make them major gold-producing areas for much of history. Putting in additives that modify the properties of glass is problematic, because the high temperature of preparation destroys most of them. Egyptian hieroglyphs from as early as 2600 BC describe gold, which king Tushratta of the Mitanni claimed was as "common as dust" in Egypt. An innovative way for making glass involves preparation by polymerization. It may have been the first metal used by humans and was valued for ornamentation and rituals. Large amounts of iron are used in glass that absorbs infrared energy, such as heat absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs UV wavelengths (biologically damaging ionizing radiation). Gold ( Sanskrit jval, Greek χρυσóς [khrisós], Latin aurum for "shining dawn", Anglo-Saxon gold, Chinese 金 [jīn],Japanese 金 [kin] ) has been known and highly valued since prehistoric times.

Thorium oxide gives glass a high refractive index and low dispersion, and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern glasses. Because of its high electrical conductivity and resistance to corrosion and other desirable combinations of physical and chemical properties, gold also emerged in the late 20th century as an essential industrial metal. Adding barium also increases the refractive index. Gold and its many alloys are most often used in jewelry, coinage and as a standard for monetary exchange in many countries. Lead glass, such as lead crystal or flint glass, is more 'brilliant' because the increased refractive index causes noticeably more "sparkles", while boron may be added to change the thermal and electrical properties, as in Pyrex. Pure gold is too soft for ordinary use and is hardened by alloying with silver, copper, and other metals. As well as soda and lime, most common glass has other ingredients added to change its properties. [1].

Soda-lime glasses account for about 90% of manufactured glass. Recent research undertaken by Frank Reith of the Australian National University shows that microbes play an important role in the formation of gold deposits, transporting and precipitating gold to form grains and nuggets that collect in alluvial deposits. The resulting glass contains about 70% silica and is called a soda-lime glass. The added metal is oxidized and dissolves allowing the gold to be displaced from solution and be recovered as a solid precipitate. However, the soda makes the glass water-soluble, which is obviously undesirable, so lime (calcium oxide, CaO) is the third component, added to restore insolubility. Gold ions in solution are readily reduced and precipitated out as gold metal by the addition of virtually any other metal as the reducing agent. One is soda (sodium carbonate Na2CO3), or potash, the equivalent potassium compound, which lowers the melting point to about 1000 °C (1800 °F). Common oxidation states of gold include +1 (gold(I) or aurous compounds) and +3 (gold(III) or auric compounds).

Pure silica (SiO2) has a melting point of about 2000 °C (3600 °F), and while it can be made into glass for special applications (see fused quartz), two other substances are always added to common glass to simplify processing. Heat, moisture, oxygen, and most corrosive agents have very little chemical effect on gold, making it well-suited for use in coins and jewelry; conversely, halogens will chemically alter gold, and aqua regia dissolves it. Collecting obsidian from national parks and some places may be prohibited by law, but the same toolmaking techniques can be applied to industrially-made glass. Gold is a good conductor of heat and electricity, and is not affected by air and most reagents. Obsidian is a raw material for flint knappers, who have used it to make extremely sharp knives since the stone age. As the amount of silver increases, the color becomes whiter and the specific gravity lower. This glass is called obsidian, and is usually black with impurities. Native gold contains usually eight to ten per cent silver, but often much more — alloys with a silver content over 20% are called electrum.

Glass is sometimes created naturally from volcanic magma. Adding copper yields a redder metal, iron blue, Silver produces green, aluminium purple, platinum metals white, and natural bismuth together with silver alloys produce black. The glasses are arranged by composition, refractive index, and Abbe number. This can be done to increase its strength, or create several exotic colors, sold for instance in the western United States to the tourist trade as "Black Hills" gold. For example, BK7 is a low-dispersion borosilicate crown glass, and SF10 is a high-dispersion dense flint glass. A soft metal, gold will readily form alloys with many other metals. Glasses used for making optical devices are commonly categorized using a six-digit glass code, or alternatively a letter-number code from the Schott Glass catalogue. It is the most malleable and ductile metal known; a single gram can be beaten into a sheet of one square metre, or an ounce into 300 square feet.

Amorphous SiO2 is also used as a dielectric material in integrated circuits, due to the smooth and electrically neutral interface it forms with silicon. Only silver colloids exhibit the same interactions with light, albeit at a shorter frequency, making silver colloids yellow in color. Undersea cables have sections doped with erbium, which amplify transmitted signals by laser emission from within the glass itself. These colors are the result of gold's plasmon frequency lying in the visible range, which causes red and yellow light to be reflected, and blue light to be absorbed. Individual fibres are given an equally transparent core of SiO2/GeO2 glass, which has only slightly different optical properties (the germanium contributing to a higher index of refraction). Gold is a metallic element with a characteristic yellow color, but can also be black or ruby when finely divided, while colloidal solutions are intensely colored and often purple. This type of glass can be made so pure that hundreds of kilometres of glass are transparent at infrared wavelengths in fibre optic cables. .

Pure SiO2 glass (also called fused quartz) does not absorb UV light and is used for applications that require transparency in this region, although it is more expensive. Its ISO currency code is XAU. This is due to the addition of compounds such as soda ash (sodium carbonate). Gold forms the basis for a monetary standard used by the International Monetary Fund (IMF) and the Bank for International Settlements (BIS). Ordinary glass does not allow light at a wavelength of lower than 400 nm, also known as ultraviolet light or UV, to pass. For millennia, gold has served as money and is also used in jewelry, dentistry, and in electronics. The transparency is due to an absence of electronic transition states in the range of visible light, and to the fact that such glass is homogeneous on all length scales greater than about a wavelength of visible light (inhomogeneities cause light to be scattered, breaking up any coherent image transmission). The metal occurs as nuggets or grains in rocks and in alluvial deposits and is one of the coinage metals.

One of the most obvious characteristics of ordinary glass is that it is transparent to visible light (not all glassy materials are). A soft, shiny, yellow, dense, malleable, ductile (trivalent and univalent) transition metal, gold does not react with most chemicals but is attacked by chlorine, fluorine and aqua regia. Common glass contains about 70% amorphous silicon dioxide (SiO2), which is the same chemical compound found in quartz, and its polycrystalline form, sand. Gold is a chemical element in the periodic table that has the symbol Au (from the Latin aurum) and atomic number 79. These properties can be modified, or even changed entirely, with the addition of other compounds or heat treatment. The Columbia Electronic Encyclopedia, 6th ed. Glass is, however, brittle and will break into sharp shards. Los Alamos National Laboratory – Gold.

These desirable properties lead to a great many uses of glass. Gold hydrazide: an olive-green powder, AuN2H3, one of several explosive compounds known archaically as aurum fulminans. In its pure form, glass is a transparent, relatively strong, hard-wearing, essentially inert, and biologically inactive material which can be formed with very smooth and impervious surfaces. Gold cluster compounds. The remainder of this article will be concerned with a specific type of glass—the silica-based glasses in common use as a building, container or decorative material. Gold chalcogenides (O, S, Se,Te). The term enamel is used to describe glass fused as a decorative or functional coating on metal. Gold halides (F,Cl,Br,I).

Germanic tribes used the word glaes to describe amber, recorded by Roman historians as glaesum. Anglo-Saxons used the word glaer for amber. The AuCl4- ion after dissolving in aqua regia. glaes. Green gold (a gold/silver alloy) is used in specialized jewelry while gold alloys with copper (reddish color) are more widely used for that purpose (rose gold)*. glas, A.S. White gold (an alloy of gold with platinum, palladium, nickel, and/or zinc) serves as a substitute for platinum. The word glass comes from Latin glacies (ice) and corresponds to German Glas, M.E. Only the salts and radioisotopes (mentioned above) have any evidence of medicinal value.

The resulting solid is amorphous, not crystalline like the sugar was originally, which can be seen in its conchoidal fracture. For similar reasons, it also used as the basis for some superstitious, over the top, health claims. A simple example is when table sugar is melted and cooled rapidly by dumping the liquid sugar onto a cold surface. Some use it as an excuse to create super-expensive delicacies ($1,000 cocktails). The materials definition of a glass is a uniform amorphous solid material, usually produced when a suitably viscous molten material cools very rapidly to below its glass transition temperature, thereby not giving enough time for a regular crystal lattice to form. Having no reactivity it adds no taste but is taken as a delicacy. . Called varak or (varaq) in India.

This (along with chromatic aberration and other effects) limits the size of refracting telescopes, with the largest refractor in the World being the Yerkes Observatory telescope with a diameter of 102cm. Gold flake is used on and in some gourmet sweets and drinks. The result is a loss of focus and is sometimes argued to occur not because of the liquid properties of glass but rather sagging of the telescope itself, but this is not correct. The gold isotope Au-198, (half-life: 2.7 days) is used in some cancer treatments and for treating other diseases. This sag happens because the lens is only supported around its edge. However, it can also cause photosensitive rashes, gastrointestinal disturbance, and kidney damage. Glass in Refracting Telescopes, with objective lenses greater than 105cm in diameter, is observed to sag under its own under weight over time. It inhibits lymphocyte proliferation, lysosomal enzyme release, the release of reactive oxygen species from macrophages, and IL-1 production.

Similarly, it should not be possible to see Newton's rings between decade-old fragments of window glass—but this can in fact be quite easily done. Disodium aurothiomalate is a treatment for rheumatoid arthritis (administered intramuscularly). If glass flows at a rate that allows changes to be seen with the naked eye after centuries, then changes in optical telescope mirrors should be observable (by interferometry) in a matter of days—but this also is not observed. Since it is a good reflector of both infrared and visible light, it is used for the protective coatings on many artificial satellites. If medieval glass has flowed perceptibly, then ancient Roman and Egyptian objects should have flowed proportionately more—but this is not observed. Many competitions and honors, such as the Olympics and the Nobel Prize, award a gold medal to the winner (with silver to the second-place finisher, and bronze to the third.). In layperson's terms, he wrote that glass at room temperature is very strongly on the solid side of the spectrum from solids to liquids. Gold is used as a coating enabling biological material to be viewed under a scanning electron microscope.

Phys, 66(5):392-5, May 1998). It is also the usual starting point for making other gold compounds. J. Gold(III) chloride is used as a catalyst in organic chemistry. Hence, the relaxation period (characteristic flow time) of cathedral glasses would be even longer" (Am. Chlorauric acid is used in photography for toning the silver image. Zanotto states "...the predicted relaxation time for GeO2 at room temperature is 1032 years. It is also the form used as gold paint on ceramics prior to firing.

Writing in the American Journal of Physics, physicist Edgar D. Colloidal gold (a gold nanoparticle) is an intensely colored solution that is currently studied in many labs for medical, biological and other applications. double-glazing. Gold is used in restorative dentistry especially in tooth restorations such as crowns and bridges. application of a self-cleaning catylist. The resistance to oxidation of gold has led to its widespread use as thin layers electroplated on the surface of electrical connectors to ensure a good connection. chemical strengthening. Gold performs critical functions in computers, communications equipment, spacecraft, jet aircraft engines, and a host of other products.

toughening. Gold can be made into thread and used in embroidery. laminating. figure rolled glass. float (annealed) glass.

polished plate glass. rolled plate glass. sheet glass. cylinder glass.