Aluminium

General Name, Symbol, Number aluminium, Al, 13 Chemical series poor metals Group, Period, Block 13, 3, p Appearance silvery
Atomic mass 26.9815386(8) g/mol Electron configuration [Ne] 3s2 3p1 Electrons per shell 2, 8, 3 Physical properties Phase solid Density (near r.t.) 2.70 g/cm³ Liquid density at m.p. 2.375 g/cm³ Melting point 933.47 K
(660.32 °C, 1220.58 °F) Boiling point 2792 K
(2519 °C, 4566 °F) Heat of fusion 10.71 kJ/mol Heat of vaporization 294.0 kJ/mol Heat capacity (25 °C) 24.200 J/(mol·K) Atomic properties Crystal structure cubic face centered Oxidation states 3
(amphoteric oxide) Electronegativity 1.61 (Pauling scale) Ionization energies
(more) 1st: 577.5 kJ/mol 2nd: 1816.7 kJ/mol 3rd: 2744.8 kJ/mol Atomic radius 125 pm Atomic radius (calc.) 118 pm Covalent radius 118 pm Miscellaneous Magnetic ordering paramagnetic Electrical resistivity (20 °C) 26.50 nΩ·m Thermal conductivity (300 K) 237 W/(m·K) Thermal expansion (25 °C) 23.1 µm/(m·K) Speed of sound (thin rod) (r.t.) (rolled) 5000 m/s Young's modulus 70 GPa Shear modulus 26 GPa Bulk modulus 76 GPa Poisson ratio 0.35 Mohs hardness 2.75 Vickers hardness 167 MPa Brinell hardness 245 MPa CAS registry number 7429-90-5 Notable isotopes References

Aluminium or aluminum (see the spelling section below) is the chemical element in the periodic table that has the symbol Al and atomic number 13. It is a silvery and ductile member of the poor metal group of chemical elements. Aluminium is found primarily as the ore bauxite and is remarkable for its resistance to oxidation (due to the phenomenon of passivation) and its light weight. Aluminium is used in many industries to make millions of different products and is very important to the world economy. Structural components made from aluminium and its alloys are vital to the aerospace industry and very important in other areas of transportation and building in which light weight, durability, and strength are needed.

Properties

A piece of aluminium metal about 15 centimetres long.

Aluminium is a soft and lightweight metal with a dull silvery appearance, due to a thin layer of oxidation that forms quickly when it is exposed to air. Aluminium is nontoxic (as the metal), non-magnetic, and non-sparking. Pure aluminium has a tensile strength of about 49 megapascals (MPa) and 700 MPa if it is formed into an alloy. Aluminium is about one-third as dense as steel or copper; is malleable, ductile, and easily machined and cast; and has excellent corrosion resistance and durability due to the protective oxide layer. Aluminium mirror finish has the highest reflectance of any metal in the 200-400 nm (UV) , and the 3000-10000 nm (far IR) regions, while in the 400-700 nm visible range it is slightly outdone by silver, and in the 700-3000 (near IR) by silver, gold and copper. It is the second most malleable metal (after gold) and the sixth most ductile.

Bohr Diagram.

Applications

Whether measured in terms of quantity or value, the use of aluminium exceeds that of any other metal except iron, and it is important in virtually all segments of the world economy.

Pure aluminium has a low tensile strength, but readily forms alloys with many elements such as copper, zinc, magnesium, manganese and silicon (e.g.duralumin). Today almost all materials that claim to be aluminium are actually an alloy thereof. Pure aluminium is encountered only when corrosion resistance is more important than strength or hardness. Conversely, the term "alloy" in general use today usually means aluminium alloy.

When combined with thermo-mechanical processing aluminium alloys display a marked improvement in mechanical properties. Aluminium alloys form vital components of aircraft and rockets as a result of their high strength to weight ratio.

When aluminium is evaporated in a vacuum it forms a coating that reflects both visible light and infrared. These coatings form a thin layer of protective aluminium oxide that does not deteriorate as silver coatings do. In particular, nearly all modern mirrors are made using a thin reflective coating of aluminium on the back surface of a sheet of float glass. Telescope mirrors are also coated with a thin layer of aluminium, but are front coated to avoid internal reflections even though this makes the surface more susceptible to damage.


An aluminium can used for the soft drink Diet Coke.

Some of the many uses for aluminium are in:

Aluminium oxide, alumina, is found naturally as corundum (rubies and sapphires), emery, and is used in glass making. Synthetic ruby and sapphire are used in lasers for the production of coherent light.

Aluminium oxidises very energetically and as a result has found use in solid rocket fuels, thermite, and other pyrotechnic compositions.

Aluminium is also a superconductor, with a superconducting critical temperature of 1.2 kelvins.

Engineering use

Aluminium alloys with a wide range of properties are used in engineering structures. Alloy systems are classified by a number system (ANSI) or by names indicating their main alloying constituents (DIN and ISO). Selecting the right alloy for a given application entails considerations of strength, ductility, formability, weldability and corrosion resistance to name a few. A brief historical overview of alloys and manufacturing technologies is given in Ref. [1].

Improper use of aluminium can result in problems, particularly in contrast to iron or steel, which appear "better behaved" to the intuitive designer, mechanic, or technician. The reduction by two thirds of the weight of an aluminium part compared to a similarly sized iron or steel part seems enormously attractive, but it should be noted that it is accompanied by a reduction by two thirds in the stiffness of the part. Therefore, although direct replacement of an iron or steel part with a duplicate made from aluminium may still give acceptable strength to withstand peak loads, the increased flexibility will cause three times more deflection in the part.

Where failure is not an issue but excessive flex is undesirable due to requirements for precision of location or efficiency of transmission of power, simple replacement of steel tubing with similarly sized aluminium tubing will result in a degree of flex which is undesirable; for instance, the increased flex under operating loads caused by replacing steel bicycle frame tubing with aluminium tubing of identical dimensions will cause misalignment of the power-train as well as absorbing the operating force. To increase the rigidity by increasing the thickness of the walls of the tubing increases the weight proportionately, so that the advantages of lighter weight are lost as the rigidity is restored.

Aluminium can best be used by redesigning the part to suit its characteristics; for instance making a bicycle of aluminium tubing which has an oversize diameter rather than thicker walls. In this way, rigidity can be restored or even enhanced without increasing weight. The limit to this process is the increase in susceptibility to what is termed "buckling" failure, where the deviation of the force from any direction other than directly along the axis of the tubing causes folding of the walls of the tubing.

The latest models of the Corvette automobile, among others, are a good example of redesigning parts to make best use of aluminium's advantages. The aluminium chassis members and suspension parts of these cars have large overall dimensions for stiffness but are lightened by reducing cross-sectional area and removing unneeded metal; as a result, they are not only equally or more durable and stiff as the usual steel parts, but they possess an airy gracefulness which most people find attractive. Similarly, aluminium bicycle frames can be optimally designed so as to provide rigidity where required, yet have flexibility in terms of absorbing the shock of bumps from the road and not transmitting them to the rider.

The strength and durability of aluminium varies widely, not only as a result of the components of the specific alloy, but also as a result of the particular manufacturing process; for this reason, it has from time to time gained a bad reputation. For instance, a high frequency of failure in many early aluminium bicycle frames in the 1970s resulted in just such a poor reputation; with a moment's reflection, however, the widespread use of aluminium components in the aerospace and automotive high performance industries, where huge stresses are undergone with vanishingly small failure rates, proves that properly built aluminium bicycle components should not be unusually unreliable, and this has subsequently proved to be the case.

Similarly, use of aluminium in automotive applications, particularly in engine parts which must survive in difficult conditions, has benefited from development over time. An Audi engineer commented about the V12 engine, producing over 500 horsepower (370 kW), of an Auto Union race car of the 1930s which was recently restored by the Audi factory, that the aluminium alloy of which the engine was constructed would today be used only for lawn furniture and the like. Even the aluminium cylinder heads and crankcase of the Corvair, built as recently as the 1960s, earned a reputation for failure and stripping of threads in holes, even as large as spark plug holes, which is not seen in current aluminium cylinder heads.

Often, aluminium's sensitivity to heat must also be considered. Even a relatively routine workshop procedure involving heating is complicated by the fact that aluminium, as opposed to steels, will melt without first turning red. Forming operations where a blow torch is used therefore requires some expertise since no visual signs reveal how close the material is to melting. Aluminium also will accumulate internal stresses and strains under conditions of overheating; while not immediately obvious, the tendency of the metal to "creep" under sustained stresses results in delayed distortions, for instance the commonly observed warping or cracking of aluminium automobile cylinder heads after an engine is overheated, sometimes as long as years later, or the tendency of welded aluminium bicycle frames to gradually twist out of alignment from the stresses accumulated during the welding process. For this reason, many uses of aluminium in the aerospace industry avoid heat altogether by joining parts using adhesives; this was also used for some of the early aluminium bicycle frames in the 1970s, with unfortunate results when the aluminium tubing corroded slightly, loosening the bond of the adhesive and leading to failure of the frame. Stresses from overheating aluminium can be relieved by heat-treating the parts in an oven and gradually cooling, in effect annealing the stresses; this can also result, however, in the part becoming distorted as a result of these stresses, so that such heat-treating of welded bicycle frames, for instance, results in a significant fraction becoming misaligned. If the misalignment is not too severe, once cooled they can be bent back into alignment with no negative consequences; of course, if the frame is properly designed for rigidity (see above), this will require enormous force.

Household wiring

Because of its high conductivity and relatively low price compared to copper at the time, aluminium was introduced for household electrical wiring to a large degree in the United States in the 1960s. Unfortunately, many of the wiring fixtures at the time were not designed to accept aluminium wire. More specifically:

In combination, these properties caused connections between electrical fixtures and aluminium wiring to overheat which resulted in several fires. As a result, aluminium household wiring has become unpopular, and in many jurisdictions it is not permitted in very small sizes in new construction. However, aluminium wiring can be safely used with fixtures whose connections are designed to avoid loosening and overheating. Older fixtures of this type are marked "Al/Cu", and newer ones are marked "CO/ALR". Otherwise, aluminium wiring can be terminated by crimping it to a short "pigtail" of copper wire, which can be treated as any other copper wire. A properly done crimp, requiring high pressure produced by the proper tool, is tight enough not only to eliminate any thermal expansion of the aluminium, but also to exclude any atmospheric oxygen and thus prevent corrosion between dissimilar metals. New alloys are used for aluminium building wire today in combination with aluminium terminations. Connections made with these standard industry products are as safe and reliable as copper connections.

History

The ancient Greeks and Romans used salts of this metal as dyeing mordants and as astringents for dressing wounds, and alum is still used as a styptic. Further Joseph Needham suggested finds in 1974 showed the ancient Chinese used aluminium (see "notes" linked above). In 1761 Guyton de Morveau suggested calling the base alum 'alumine'. In 1808, Humphry Davy identified the existence of a metal base of alum, which he named (see Spelling section).

Friedrich Wöhler is generally credited with isolating aluminium (Latin alumen, alum) in 1827 by mixing anhydrous aluminium chloride with potassium. However, the metal had been produced for the first time two years earlier in an impure form by the Danish physicist and chemist Hans Christian Ørsted. Therefore almanacs and chemistry sites often list Øersted as the discoverer of aluminium.[2] Still it would further be P. Berthier who discovered aluminium in bauxite ore and successfully extracted it. The Frenchman Henri Saint-Claire Deville improved Wöhler's method in 1846 and described his improvements in a book in 1859, chief among these being the substitution of sodium for the considerably more expensive potassium.

The American Charles Martin Hall of Oberlin, OH applied for a patent (400655) in 1886 for an electrolytic process to extract aluminium using the same technique that was independently being developed by the Frenchman Paul Héroult in Europe. The invention of the Hall-Héroult process in 1886 made extracting aluminium from minerals cheaper, and is now the principal method in common use throughout the world. Upon approval of his patent in 1889, Hall, with the financial backing of Alfred E. Hunt of Pittsburgh, PA, started the Pittsburgh Reduction Company, renamed to Aluminum Company of America in 1907, later shortened to Alcoa.

The statue known as Eros in Piccadilly Circus London, was made in 1893 and is one of the first statues to be cast in aluminium.

Aluminium was selected as the material to be used for the apex of the Washington Monument, at a time when one ounce cost twice the daily wages of a common worker in the project. [3]

Germany became the world leader in aluminium production soon after Adolf Hitler seized power. By 1942, however, new hydroelectric power projects such as the Grand Coulee Dam gave the United States something Nazi Germany could not hope to compete with, namely the capability of producing enough aluminium to manufacture sixty thousand warplanes in four years. [4]

Natural occurrence

Although aluminium is the most abundant metallic element in Earth's crust (believed to be 7.5% to 8.1%), it is very rare in its free form and was once considered a precious metal more valuable than gold. Napoleon III of France had a set of aluminium plates reserved for his finest guests. Others had to make do with gold ones. Aluminium has been produced in commercial quantities for just over 100 years.

Aluminium was, when it was first discovered, extremely difficult to separate from its ore. Aluminium is among the most difficult metals on Earth to refine, despite the fact that it is one of the planet's most common. The reason is that aluminium is oxidised very rapidly and that its oxide is an extremely stable compound that, unlike rust on iron, does not flake off. The very reason for which aluminium is used in many applications is why it is so hard to produce.

Recovery of this metal from scrap (via recycling) has become an important component of the aluminium industry. Recycling involves simply melting the metal, which is far less expensive than creating it from ore. Refining aluminium requires enormous amounts of electricity; recycling it requires only 5% of the energy to produce it. A common practice since the early 1900s, aluminium recycling is not new. It was, however, a low-profile activity until the late 1960s when the exploding popularity of aluminium beverage cans finally placed recycling into the public consciousness. Other sources for recycled aluminium include automobile parts, windows and doors, appliances, containers and other products.

Aluminium is a reactive metal and it is hard to extract it from its ore, aluminium oxide (Al2O3). Direct reduction, with carbon for example, is not economically viable since aluminium oxide has a melting point of about 2000 °C. Therefore, it is extracted by electrolysis — the aluminium oxide is dissolved in molten cryolite and then reduced to the pure metal. By this process, the actual operational temperature of the reduction cells is around 950 to 980 °C. Cryolite was originally found as a mineral on Greenland, but has been replaced by a synthetic cryolite. Cryolite is a mixture of aluminium, sodium, and calcium fluorides: (Na3AlF6). The aluminium oxide (a white powder) is obtained by refining bauxite, which is red since it contains 30 to 40% iron oxide. This is done using the so-called Bayer process. Previously, the Deville process was the predominant refining technology.

The electolytic process replaced the Wöhler process, which involved the reduction of anhydrous aluminium chloride with potassium. Both of the electrodes used in the electrolysis of aluminium oxide are carbon. Once the ore is in the molten state, its ions are free to move around. The reaction at the negative cathode is

Here the aluminium ion is being reduced (electrons are added). The aluminium metal then sinks to the bottom and is tapped off.

At the positive electrode (anode) oxygen gas is formed:

This carbon anode is then oxidised by the oxygen. The anodes in a reduction must therefore be replaced regularly, since they are consumed in the process:

Contrary to the anodes, the cathodes are not consumed during the operation, since there is no oxygen present at the cathode. The carbon cathode is protected by the liquid aluminium inside the cells. Cathodes do erode, mainly due to electrochemical processes. After 5 to 10 years, depending on the current used in the electrolysis, a cell has to be reconstructed completely, because the cathodes are completely worn.

Aluminium electrolysis with the Hall-Héroult process consumes a lot of energy, but alternative processes were always found to be less viable economically and/or ecologically. The world-wide average specific energy consumption is approximately 15±0.5 kilowatt-hours per kilogram of aluminium produced (52 to 56 MJ/kg). The most modern smelters reach approximately 12.8 kW·h/kg (46.1 MJ/kg). Reduction line current for older technologies are typically 100 to 200 kA. State-of-the-art smelters operate with about 350 kA. Trials have been reported with 500 kA cells.

Electric power represents about 20 to 40% of the cost of producing aluminium, depending on the location of the aluminium smelter. Smelters tend to be located where electric power is plentiful and inexpensive, such as South Africa, the South Island of New Zealand, Australia, China, Middle-East, Russia, Iceland and Quebec in Canada.

In 2004, China was the top world producer of aluminium. Suriname depends on aluminium exports for 70% of its export earnings.[5]

see also category:Aluminium minerals

Isotopes

Aluminium has nine isotopes, whose mass numbers range from 23 to 30. Only 27Al (stable isotope) and 26Al (radioactive isotope, t1/2 = 7.2 × 105 y) occur naturally, however 27Al has a natural abundance of 100%. 26Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Aluminium isotopes have found practical application in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The ratio of 26Al to 10Be has been used to study the role of transport, deposition, sediment storage, burial times, and erosion on 105 to 106 year time scales.

Cosmogenic 26Al was first applied in studies of the Moon and meteorites. Meteorite fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their travel through space, causing substantial 26Al production. After falling to Earth, atmospheric shielding protects the meteorite fragments from further 26Al production, and its decay can then be used to determine the meteorite's terrestrial age. Meteorite research has also shown that 26Al was relatively abundant at the time of formation of our planetary system. Possibly, the energy released by the decay of 26Al was responsible for the remelting and differentiation of some asteroids after their formation 4.6 billion years ago.

Clusters

In the journal Science of 14 January 2005 it was reported that clusters of 13 aluminium atoms (Al13) had been made to behave like an iodine atom; and, 14 aluminium atoms (Al14) behaved like an alkaline earth atom. The researchers also bound 12 iodine atoms to an Al13 cluster to form a new class of polyiodide. This discovery is reported to give rise to the possibility of a new characterisation of the periodic table: superatoms. The research teams were led by Shiv N. Khanna (Virginia Commonwealth University) and A. Welford Castleman Jr (Penn State University). [6]

Precautions

Aluminium is one of the few abundant elements that appears to have no beneficial function in living cells, but a few percent of people are allergic to it — they experience contact dermatitis from any form of it: an itchy rash from using styptic or antiperspirant products, digestive disorders and inability to absorb nutrients from eating food cooked in aluminium pans, and vomiting and other symptoms of poisoning from ingesting such products as Rolaids , Amphojel, and Maalox (antacids). In other people, aluminium is not considered as toxic as heavy metals, but there is evidence of some toxicity if it is consumed in excessive amounts, although the use of aluminium cookware, popular because of its corrosion resistance and good heat conduction, has not been shown to lead to aluminium toxicity in general. Excessive consumption of antacids containing aluminium compounds and excessive use of aluminium-containing antiperspirants are more likely causes of toxicity. It has been suggested that aluminium may be linked to Alzheimer's disease, although that research has recently been refuted; aluminium accumulation may be a consequence of the Alzheimer's damage, not the cause. In any event, if there is any toxicity of aluminium it must be via a very specific mechanism, since total human exposure to the element in the form of naturally occurring clay in soil and dust is enormously large over a lifetime.

Care must be taken to prevent aluminium from coming into contact with certain chemicals that can cause it to corrode quickly. For example, just a small amount of mercury applied to the surface of a piece of aluminium can break up the aluminium oxide barrier usually present. Within a few hours, even a heavy structural beam can be significantly weakened. For this reason, mercury thermometers are not allowed on many airliners, as aluminium is a common structural component in aircraft.

Spelling

Etymology/Nomenclature history

In 1808, Humphry Davy originally proposed the name alumium while trying to isolate the new metal electrolytically from the mineral alumina. In 1812 he changed the name to aluminum to match its Latin root. The same year, an anonymous contributor to the Quarterly Review objected to aluminum, and proposed the name aluminium.

Aluminium, for so we shall take the liberty of writing the word, in preference to aluminum, which has a less classical sound. (Q. Review VIII. 72, 1812)

This had the advantage of conforming to the -ium suffix precedent set by other newly discovered elements of the period: potassium, sodium, magnesium, calcium, and strontium (all of which Davy had isolated himself). Nevertheless, -um spellings for elements were not unknown at the time: platinum, which had been known to Europeans since the 16th century, molybdenum, which was discovered in 1778, and tantalum, which was discovered in 1802, all have spellings ending in -um.

Curiously, the United States adopted the -ium for most of the 19th century with aluminium appearing in Webster's Dictionary of 1828. However in 1892 Charles Martin Hall used the -um spelling in an advertising handbill for his new efficient electrolytic method for the production of aluminium, despite using the -ium spelling in all of his patents filed between 1886 and 1903. It has consequently been suggested that the spelling on the flyer was a simple spelling mistake rather than a deliberate choice to use the -um spelling. Hall's domination of production of the metal ensured that the spelling aluminum became the standard in North America, even though the Webster Unabridged Dictionary of 1913 continued to use the -ium version.

In 1926, the American Chemical Society officially decided to use aluminum in its publications, and American dictionaries typically label the spelling aluminium as a British variant.

Present-day spelling

In the English-speaking world, the spellings (and associated pronunciations) aluminium and aluminum are both in common use in scientific and nonscientific contexts. In the United States, the spelling aluminium is largely unknown, and the spelling aluminum predominates. Elsewhere in the English-speaking world the spelling aluminium predominates, and the spelling aluminum is largely unknown. However, in Canada both spellings are common, due to the multiple influences on the language of its proximity to the United States, its British colonial past and the large number of native French speakers.

Outside English, the "ium" spelling is widespread: the word is aluminium in French and German, and identical or similar forms are used in many other languages. Consequently it is the more common of the two spellings in global terms, even though there may be more users of aluminum in the English-speaking world.

The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990, but three years later recognised aluminum as an acceptable variant. Hence their periodic table includes both, but places aluminium first [7]. IUPAC officially prefers the use of aluminium in its internal publications, although several IUPAC publications use the spelling aluminum.[8]

Chemistry

Oxidation state 1

Oxidation state 2

Oxidation state 3

Aluminium in popular culture


This page about Aluminum includes information from a Wikipedia article.
Additional articles about Aluminum
News stories about Aluminum
External links for Aluminum
Videos for Aluminum
Wikis about Aluminum
Discussion Groups about Aluminum
Blogs about Aluminum
Images of Aluminum

IUPAC officially prefers the use of aluminium in its internal publications, although several IUPAC publications use the spelling aluminum.[8]. The following is a partial list of concept cars.. Hence their periodic table includes both, but places aluminium first [7]. The following is a list of models Audi ostensibly plans to offer in the future.. The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990, but three years later recognised aluminum as an acceptable variant. Audi now has an impressive range of cars, engines and transmissions available, which continue to lead the way and introduce new technologies into the market. Consequently it is the more common of the two spellings in global terms, even though there may be more users of aluminum in the English-speaking world. Recent examples of this include DSG and FSI.

Outside English, the "ium" spelling is widespread: the word is aluminium in French and German, and identical or similar forms are used in many other languages. As a premium member of the VW Group, technologies are frequently first introduced to the mass market with Audi vehicles before being 'trickled down' to more value oriented brands such as VW, SEAT and Škoda. However, in Canada both spellings are common, due to the multiple influences on the language of its proximity to the United States, its British colonial past and the large number of native French speakers. This is a direct fuel-injection technique that Audi had also used on its diesel engines since the early 1980s. Elsewhere in the English-speaking world the spelling aluminium predominates, and the spelling aluminum is largely unknown. Audi has now introduced FSI on some of their engines, including the 1.6 L 4 cylinder, a new 2.0 L (Audi was the first manufacturer in the world to utilize a turbo charger and FSI on the same powerplant), and the 3.1 L V6. In the United States, the spelling aluminium is largely unknown, and the spelling aluminum predominates. New models of the A3, A4, A6 and A8 have been introduced, with the 1.8 L engine now 2.0 L and the 3.0 L V6 is now 3.1 L in size.

In the English-speaking world, the spellings (and associated pronunciations) aluminium and aluminum are both in common use in scientific and nonscientific contexts. The engine range was continually upgraded, with a 2.7 L twin turbo V6 being offered in the Audi S4, A6 and allroad, the 2.8 L V6 was replaced by a 3.0 L unit. In 1926, the American Chemical Society officially decided to use aluminum in its publications, and American dictionaries typically label the spelling aluminium as a British variant. This is implemented in some Volkswagen Golf, Audi A3 and TT models. Hall's domination of production of the metal ensured that the spelling aluminum became the standard in North America, even though the Webster Unabridged Dictionary of 1913 continued to use the -ium version. The system includes dual electrohydraulically controlled clutches instead of a torque converter. It has consequently been suggested that the spelling on the flyer was a simple spelling mistake rather than a deliberate choice to use the -um spelling. At the turn of the century, Audi introduced the direct shift gearbox (DSG), a manual transmission driveable like an automatic transmission.

However in 1892 Charles Martin Hall used the -um spelling in an advertising handbill for his new efficient electrolytic method for the production of aluminium, despite using the -ium spelling in all of his patents filed between 1886 and 1903. Further engines were added along the way, including a 3.7 L V8 and 6.0 L W12 for the A8. Curiously, the United States adopted the -ium for most of the 19th century with aluminium appearing in Webster's Dictionary of 1828. The V6's were replaced by new 2.4 and 2.8 L 30V V6's in 1998, with marked improvement in power, torque and smoothness. Nevertheless, -um spellings for elements were not unknown at the time: platinum, which had been known to Europeans since the 16th century, molybdenum, which was discovered in 1778, and tantalum, which was discovered in 1802, all have spellings ending in -um. The engines available throughout the range were now a 1.4 L, 1.6 L and 1.8 L 4 cylinder, 1.8 turbo, 2.6 L and 2.8 L V6, 2.2 L turbo-charged 5 cylinder and the 4.2 L V8. This had the advantage of conforming to the -ium suffix precedent set by other newly discovered elements of the period: potassium, sodium, magnesium, calcium, and strontium (all of which Davy had isolated himself). The model sold relatively well in Europe, however Audi decided not to develop a new model and it has since been discontinued as of 2004.

72, 1812). Another interesting model introduced was the Mercedes-Benz A-Class competitor, the Audi A2. Review VIII. A new A3 (based on the Volkswagen Golf) was introduced to the range in 1997, and the radical TT coupe and roadster were debuted in 1998 based on the same underpinnings. (Q. The Audi Cabriolet continued on (based on the Audi 80 platform) until 1999, gaining the engine upgrades along the way. Aluminium, for so we shall take the liberty of writing the word, in preference to aluminum, which has a less classical sound. The S2 was discontinued.

The same year, an anonymous contributor to the Quarterly Review objected to aluminum, and proposed the name aluminium. This also meant the S4 became the S6 and a new S4 was introduced in the A4 body. In 1812 he changed the name to aluminum to match its Latin root. The new nomenclature scheme was applied to the Audi 100 to become the Audi A6 (with a minor facelift). In 1808, Humphry Davy originally proposed the name alumium while trying to isolate the new metal electrolytically from the mineral alumina. The next major model change was in 1995 when the Audi A4 replaced the Audi 80. For this reason, mercury thermometers are not allowed on many airliners, as aluminium is a common structural component in aircraft. The weight reduction was offset by the quattro all-wheel drive system, however it meant the car had similar performance to its rivals, but far superior handling.

Within a few hours, even a heavy structural beam can be significantly weakened. The Audi A8 replaced the V8 in 1994, with a revolutionary Aluminium Space Frame (ASF) to save weight. For example, just a small amount of mercury applied to the surface of a piece of aluminium can break up the aluminium oxide barrier usually present. These two models were the beginning of the mass produced S series of performance cars. Care must be taken to prevent aluminium from coming into contact with certain chemicals that can cause it to corrode quickly. It was fitted to the Audi Coupe and named the S2 and also to the Audi 100 body, and named the S4. In any event, if there is any toxicity of aluminium it must be via a very specific mechanism, since total human exposure to the element in the form of naturally occurring clay in soil and dust is enormously large over a lifetime. The engine, initially fitted to the 200 quattro 20V of 1991, was a derivative of the engine fitted to the Sport Quattro.

It has been suggested that aluminium may be linked to Alzheimer's disease, although that research has recently been refuted; aluminium accumulation may be a consequence of the Alzheimer's damage, not the cause. The 5 cylinder was soon dropped as a major engine choice, however a turbocharged 230BHP (169kW) version remained. Excessive consumption of antacids containing aluminium compounds and excessive use of aluminium-containing antiperspirants are more likely causes of toxicity. This engine was also fitted to a face-lifted Audi 80 (all 80 and 90 models were now badged 80 except for the USA), giving this model a choice of 4, 5 and 6 cylinder engines, in sedan, coupe and cabriolet body styles. In other people, aluminium is not considered as toxic as heavy metals, but there is evidence of some toxicity if it is consumed in excessive amounts, although the use of aluminium cookware, popular because of its corrosion resistance and good heat conduction, has not been shown to lead to aluminium toxicity in general. With the introduction of an all-new Audi 100 in 1992, Audi introduced a 2.8l V6 engine. Aluminium is one of the few abundant elements that appears to have no beneficial function in living cells, but a few percent of people are allergic to it — they experience contact dermatitis from any form of it: an itchy rash from using styptic or antiperspirant products, digestive disorders and inability to absorb nutrients from eating food cooked in aluminium pans, and vomiting and other symptoms of poisoning from ingesting such products as Rolaids , Amphojel, and Maalox (antacids). Although the five cylinder engine was a successful and very robust powerplant, it was still a little too different for the target market.

[6]. There was also a coupe version of the 80/90 with both 4 and 5 cylinder engines. Welford Castleman Jr (Penn State University). By 1991, Audi had the 4 cylinder Audi 80, the 5 cylinder Audi 90 and Audi 100, the turbocharged Audi 200 and the Audi V8. Khanna (Virginia Commonwealth University) and A. Most obvious was the new grille that was now incorprated in the bonnet. The research teams were led by Shiv N. It was essentially a new engine fitted to the Audi 100/200, but with noticeable bodywork differences.

This discovery is reported to give rise to the possibility of a new characterisation of the periodic table: superatoms. This began with the release of the Audi V8 in 1990. The researchers also bound 12 iodine atoms to an Al13 cluster to form a new class of polyiodide. Through the early 1990's, Audi began to move more towards the position of being a real competitor in it's target market against Mercedes-Benz and BMW. In the journal Science of 14 January 2005 it was reported that clusters of 13 aluminium atoms (Al13) had been made to behave like an iodine atom; and, 14 aluminium atoms (Al14) behaved like an alkaline earth atom. This range of engine capacity was a good combination of good fuel economy which was on the mind of every motorist in the 1980's, and a good amount of power the customer wants. Possibly, the energy released by the decay of 26Al was responsible for the remelting and differentiation of some asteroids after their formation 4.6 billion years ago. Before 1990, there were engines produced with a displacement between 2.0 L and 2.3 L.

Meteorite research has also shown that 26Al was relatively abundant at the time of formation of our planetary system. The 2.1 L inline 5 cylinder engine was used as a base for the rally cars in the 1980's, providing well over 400 horsepower (298 kW) after modification. After falling to Earth, atmospheric shielding protects the meteorite fragments from further 26Al production, and its decay can then be used to determine the meteorite's terrestrial age. This engine was used in not only production cars but also their race cars. Meteorite fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their travel through space, causing substantial 26Al production. In the 1980s, Audi was the champion of the inline 5 cylinder, 2.1/2.2 L engine as a longer lasting alternative to more traditional 6 cylinder engines. Cosmogenic 26Al was first applied in studies of the Moon and meteorites. Today, after many decades of class-leading technology and engineering, the name quattro is an identifiable symbol and trademark that shows would-be competitors the level of quality they have to achieve in order to attempt to compete with Audi.

The ratio of 26Al to 10Be has been used to study the role of transport, deposition, sediment storage, burial times, and erosion on 105 to 106 year time scales. Although Porsche and Mercedes-Benz offer all-wheel drive systems in some cars today, neither manufacturer was able to ride the fad and come out on top like Audi has. Aluminium isotopes have found practical application in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The system also was not popular in Porsche vehicles because owners wanted the traditional performance of the rear wheel drive they got used to in older Porsches. 26Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Unfortunately, the all-wheel drive system in the Mercedes-Benz vehicles were riddled with problems right from the design sheet. Only 27Al (stable isotope) and 26Al (radioactive isotope, t1/2 = 7.2 × 105 y) occur naturally, however 27Al has a natural abundance of 100%. In the 1980's, all-wheel drive systems in cars became a fad, and other manufacturers like Porsche and Mercedes-Benz offered all-wheel drive systems in their cars to compete in the marketplace.

Aluminium has nine isotopes, whose mass numbers range from 23 to 30. In the 1970's, some vehicle manufacturers including Audi (and Subaru) designed their own all wheel drive systems in passenger vehicles. Suriname depends on aluminium exports for 70% of its export earnings.[5]. The all-aluminium concept was extended to the company's new sub-compact, the Audi A2 which was launched in 2001. In 2004, China was the top world producer of aluminium. Audi introduced a new series of vehicles in the mid-nineties and continues to pursue leading-edge technology and high performance. Smelters tend to be located where electric power is plentiful and inexpensive, such as South Africa, the South Island of New Zealand, Australia, China, Middle-East, Russia, Iceland and Quebec in Canada. An all-aluminium car was brought forward by Audi, and in 1994 the Audi A8 was launched, which introduced aluminium space frame technology.

Electric power represents about 20 to 40% of the cost of producing aluminium, depending on the location of the aluminium smelter. Audi is the only car manufacturer that produces 100% galvanized vehicles to prevent corrosion. Trials have been reported with 500 kA cells. Its first race will likely be the 2006 12 Hours of Sebring as a race-test for the 2006 24 Hours of Le Mans. State-of-the-art smelters operate with about 350 kA. the R10 employs many new features, including a twin-turbocharged diesel engine. Reduction line current for older technologies are typically 100 to 200 kA. This also ends the long era of the R8, however its replacement for 2006, called the Audi R10, was unveiled on December 13, 2005.

The most modern smelters reach approximately 12.8 kW·h/kg (46.1 MJ/kg). The Champion team was also the first American team to win Le Mans since the Gulf Ford GT's in 1967. The world-wide average specific energy consumption is approximately 15±0.5 kilowatt-hours per kilogram of aluminium produced (52 to 56 MJ/kg). But with a team of excellent drivers and experience, both Champion R8s were able to take first and third while the ORECA team took fourth. Aluminium electrolysis with the Hall-Héroult process consumes a lot of energy, but alternative processes were always found to be less viable economically and/or ecologically. On average, the R8s were about 2-3 seconds off pace compared to the Pescarolo-Judd. After 5 to 10 years, depending on the current used in the electrolysis, a cell has to be reconstructed completely, because the cathodes are completely worn. The R8s (which were built to old LMP900 regulations) received a more narrow air inlet restrictor, cutting power, and an additional 50 kg of weight compared to the newer LMP1 chassis.

Cathodes do erode, mainly due to electrochemical processes. At the 2005 24 Hours of Le Mans, Champion Racing entered two R8s along with an R8 from the Audi PlayStation Team Oreca. The carbon cathode is protected by the liquid aluminium inside the cells. Audi returned to the winner's circle at the 2004 race, with the top three finishers all driving R8s: Audi Sport Japan Team Goh finished first, Audi Sport UK Veloqx second, and Champion Racing third. Contrary to the anodes, the cathodes are not consumed during the operation, since there is no oxygen present at the cathode. In 2003, two Bentley Speed 8s, with engines designed by Audi and driven by Joest drivers loaned to the fellow VW company, competed in the GTP class and finished the race in the top two positions, while the Champion Racing R8 finished third overall and first in the LMP900 class. The anodes in a reduction must therefore be replaced regularly, since they are consumed in the process:. Audi also sold the car to customer teams such as Champion Racing.

This carbon anode is then oxidised by the oxygen. The factory supported Joest Racing team won at Le Mans three times in a row (2000 - 2002), as well as winning every race in the American Le Mans Series in its first year. At the positive electrode (anode) oxygen gas is formed:. Beginning in 1999, Audi built the Audi R8 to compete in sports car racing, including the LMP900 class at the 24 hours of Le Mans. The aluminium metal then sinks to the bottom and is tapped off. After 4 victories in a row, the Audis were sanctioned with several negative changes that deeply affected the car's performance, although Champion Audi would still manage to win the 2004 championship. Here the aluminium ion is being reduced (electrons are added). They returned in 2004 to defend their title but a newcomer, Cadillac, gave them a run for their money.

The reaction at the negative cathode is. Once again, the quattro was superior and Champion Audi won the championship. Once the ore is in the molten state, its ions are free to move around. In the US, Champion Audi racing entered an Audi RS6 in the 2003 speedvision GT challenge, competing against Corvettes, Vipers, and smaller, more agile BMWs. Both of the electrodes used in the electrolysis of aluminium oxide are carbon. In 2004 Audi returned to touring car racing by entering two factory supported Joest Racing A4s in the Deutsche Tourenwagen Masters series. The electolytic process replaced the Wöhler process, which involved the reduction of anhydrous aluminium chloride with potassium. The quattro system would eventually be banned in 1998 by the FIA.

Previously, the Deville process was the predominant refining technology. they then switched to DTM with the Audi V8, then they turned their attention to the Super Touring. This is done using the so-called Bayer process. In 1989, Audi moved to IMSA GTO with the 90, however as they avoided the two major endurance events (Daytona and Sebring) despite winning on a regular basis, they would lose out on the title. The aluminium oxide (a white powder) is obtained by refining bauxite, which is red since it contains 30 to 40% iron oxide. As Audi moved away from rallying and into circuit racing, they chose first into America with the Trans-Am in 1988,. Cryolite is a mixture of aluminium, sodium, and calcium fluorides: (Na3AlF6). This Audi S1 started the S-series of cars for Audi which now represents an increased level of sports options and quality to the Audi line up.

Cryolite was originally found as a mineral on Greenland, but has been replaced by a synthetic cryolite. The Audi S1 enjoys a 0-60 mph (0-100 km/h) time of 2.3 s. By this process, the actual operational temperature of the reduction cells is around 950 to 980 °C. All of Audi's top drivers drove this beast, Hannu Mikkola, Stig Blomqvist, Walter Röhrl and the female driver, Michèle Mouton. Therefore, it is extracted by electrolysis — the aluminium oxide is dissolved in molten cryolite and then reduced to the pure metal. The engine was mated to a 6-speed gearbox and ran on Audi's famous all-wheel drive system. Direct reduction, with carbon for example, is not economically viable since aluminium oxide has a melting point of about 2000 °C. The Audi S1 employed Audi's time-tested 5-cylinder turbo charged engine and generated over 600 hp (447 kW).

Aluminium is a reactive metal and it is hard to extract it from its ore, aluminium oxide (Al2O3). In 1987, Walter Röhrl claimed the title for Audi setting a new record of 10:47.85 in his Audi S1 he retired from the WRC in 2 years earlier. Other sources for recycled aluminium include automobile parts, windows and doors, appliances, containers and other products. Bobby Unser used an Audi in that same year to claim a new record for the Pikes Peak Hill Climb at 11:09.22. It was, however, a low-profile activity until the late 1960s when the exploding popularity of aluminium beverage cans finally placed recycling into the public consciousness. Joaquim Santos avoided hitting spectators on one side of the road, and ended up hitting spectators on the other side. A common practice since the early 1900s, aluminium recycling is not new. In 1986, Audi formally left international rally racing following the death in Portugal of driver Joaquim Santos in his RS200.

Refining aluminium requires enormous amounts of electricity; recycling it requires only 5% of the energy to produce it. The climb race pits a driver and car to drive up a 4,302 meter high mountain in Colorado and in 1985, Michèle Mouton set a new record of 11:25.39 and being the first woman to set a Pikes Peak record. Recycling involves simply melting the metal, which is far less expensive than creating it from ore. Michèle Mouton, the first female WRC driver to win a championship and a driver for Audi, took the Sport Quattro S1, now simply called the S1 and raced in the Pikes Peak Hill Climb. Recovery of this metal from scrap (via recycling) has become an important component of the aluminium industry. Audi also received rally honors in the Hong Kong to Beijing rally in that same year. The very reason for which aluminium is used in many applications is why it is so hard to produce. After another season mired in mediocre finishes, Walter Röhrl finished the season in his Sport Quattro S1 and helped place Audi second in the manufacturer's points.

The reason is that aluminium is oxidised very rapidly and that its oxide is an extremely stable compound that, unlike rust on iron, does not flake off. In 1984 Audi launched the "Sport Quattro" car which dominated races in Monte Carlo and Sweden with Audi taking all podium finishes but succumbed to problems further into World Rally Championship contention. Aluminium is among the most difficult metals on Earth to refine, despite the fact that it is one of the planet's most common. It won competition after competition for the next two years. Aluminium was, when it was first discovered, extremely difficult to separate from its ore. Many critics doubted the viability of all-wheel-drive racers, thinking them to be too heavy and complex, yet the Quattro was an instant success, winning its first rally on its first outing. Aluminium has been produced in commercial quantities for just over 100 years. It is considered one of the most significant rally cars of all time because it was one of the first to take advantage of the then-recently changed rules which allowed the use of all-wheel-drive in competition racing.

Others had to make do with gold ones. In 1980 Audi released the Quattro, an all wheel drive turbocharged car that went on to win rallies and races worldwide. Napoleon III of France had a set of aluminium plates reserved for his finest guests. In the 1990s Audi dominated the Touring and Super Touring categories of motor racing after success in circuit racing Stateside. Although aluminium is the most abundant metallic element in Earth's crust (believed to be 7.5% to 8.1%), it is very rare in its free form and was once considered a precious metal more valuable than gold. Audi's rich tradition in motorsport began with the Auto Union in the 1930s. [4]. Audi has competed in (and sometimes dominated) numerous forms of auto racing.

By 1942, however, new hydroelectric power projects such as the Grand Coulee Dam gave the United States something Nazi Germany could not hope to compete with, namely the capability of producing enough aluminium to manufacture sixty thousand warplanes in four years. However, after 2003, with the release of the new A4, and in 2004 with the new A6, Audi's dedication to quality had finally paid off when it started to receive news reports and various vehicle critics praising Audis over Mercedes-Benz and BMW. Germany became the world leader in aluminium production soon after Adolf Hitler seized power. Though its brand still doesn't have the global cachet of Mercedes-Benz or BMW, Audi's reputation for quality and understated style has once again made it a highly desirable marque. [3]. In March of 2005, Audi is building its first two dealerships in India following its high increase in sales in that region. Aluminium was selected as the material to be used for the apex of the Washington Monument, at a time when one ounce cost twice the daily wages of a common worker in the project. The largest sales increases came from Eastern Europe (+19.3%), Africa (+17.2%) and the Middle East (+58.5%).

Hunt of Pittsburgh, PA, started the Pittsburgh Reduction Company, renamed to Aluminum Company of America in 1907, later shortened to Alcoa. Record figures were recorded from 21 out of about 50 major sales markets. Upon approval of his patent in 1889, Hall, with the financial backing of Alfred E. 2004 marked the 11th straight increase in sales, selling 779,441 vehicles worldwide. The invention of the Hall-Héroult process in 1886 made extracting aluminium from minerals cheaper, and is now the principal method in common use throughout the world. Currently, Audi's sales are growing strongly in Europe, and the company is renowned for having the best build quality of any mainstream auto manufacturer. The American Charles Martin Hall of Oberlin, OH applied for a patent (400655) in 1886 for an electrolytic process to extract aluminium using the same technique that was independently being developed by the Frenchman Paul Héroult in Europe. The turning point for Audi was the sale of the new A4 in 1996, and with the release of the A4/6/8 series, which was developed together with VW and other sister brands (so called "platforms").

The Frenchman Henri Saint-Claire Deville improved Wöhler's method in 1846 and described his improvements in a book in 1859, chief among these being the substitution of sodium for the considerably more expensive potassium. Audi had contemplated withdrawing from the American market until sales began to recover in the mid-1990s. Berthier who discovered aluminium in bauxite ore and successfully extracted it. The report immediately crushed Audi sales, and Audi renamed the affected model (The 5000 became the 100/200 in 1989, as in Germany and elsewhere). Therefore almanacs and chemistry sites often list Øersted as the discoverer of aluminium.[2] Still it would further be P. 60 Minutes ignored this fact and rigged a car to perform in an uncontrolled manner. However, the metal had been produced for the first time two years earlier in an impure form by the Danish physicist and chemist Hans Christian Ørsted. This was never an issue in Europe, as Europeans in general use manual transmission gears, and have a "feeling" for vehicle revs in comparison to the speed of the car.

Friedrich Wöhler is generally credited with isolating aluminium (Latin alumen, alum) in 1827 by mixing anhydrous aluminium chloride with potassium. US citizens are used to automatic gearboxes and only two well separated pedals). In 1808, Humphry Davy identified the existence of a metal base of alum, which he named (see Spelling section). (In race cars, when manually downshifting under heavy braking, the accelerator has to be used in order to match revs properly, so both pedals have to be close to each other to be operated by the right foot at once, toes on the brake, heels on the gas. In 1761 Guyton de Morveau suggested calling the base alum 'alumine'. Independent investigators concluded that this was most likely due to a close placement of the accelerator and brake pedals (unlike American cars), and the inability, when not paying attention, to distinguish between the two. Further Joseph Needham suggested finds in 1974 showed the ancient Chinese used aluminium (see "notes" linked above). The 60 Minutes report was based on customer reports of acceleration when the brake pedal was pushed.

The ancient Greeks and Romans used salts of this metal as dyeing mordants and as astringents for dressing wounds, and alum is still used as a styptic. This decline in sales was not helped in the USA by a 60 Minutes report which purported to show that Audi automobiles suffered from "unintended acceleration". Connections made with these standard industry products are as safe and reliable as copper connections. In the early nineties, sales began to slump for the Audi 80 series, and some basic construction problems started to surface. New alloys are used for aluminium building wire today in combination with aluminium terminations. However, its modern and dynamic exterior belied the low performance of its base engine, and its base package was quite spartan (even the passenger-side mirror was an option.) In 1987, Audi put forward a new and very elegant Audi 90, which had a much superior set of standard features. A properly done crimp, requiring high pressure produced by the proper tool, is tight enough not only to eliminate any thermal expansion of the aluminium, but also to exclude any atmospheric oxygen and thus prevent corrosion between dissimilar metals. This completely new development sold extremely well.

Otherwise, aluminium wiring can be terminated by crimping it to a short "pigtail" of copper wire, which can be treated as any other copper wire. In 1986, as the Passat-based Audi 80 was beginning to develop a kind of "grandfather's car" image, the type 89 was introduced. Older fixtures of this type are marked "Al/Cu", and newer ones are marked "CO/ALR". Prominent wins proved the viability of all-wheel drive racecars, and the Audi name became associated with advances in automotive technology,. However, aluminium wiring can be safely used with fixtures whose connections are designed to avoid loosening and overheating. Commonly referred to as the "Ur-Quattro" (the "Ur-" prefix is a German augmentative used, in this case, to mean "original" and is also applied to the first generation of Audi's S4 and S6 sport sedans, as in "UrS4" and "UrS6"), few of these vehicles were produced (all hand-built by a single team) but the model was a great success in rallying. As a result, aluminium household wiring has become unpopular, and in many jurisdictions it is not permitted in very small sizes in new construction. The performance car was named the "Quattro," a turbocharged coupé which was also the first production vehicle to feature full-time all-wheel drive through a center differential.

In combination, these properties caused connections between electrical fixtures and aluminium wiring to overheat which resulted in several fires. The Audi image at this time was a conservative one, and so, a proposal from chassis engineer Jorg Bensinger was accepted to develop the four-wheel drive technology in Volkswagen's Iltis military vehicle for an Audi performance car and rally racing car. More specifically:. This was soon joined by the Audi 80/Fox (which formed the basis for the 1973 Volkswagen Passat) in 1972. Unfortunately, many of the wiring fixtures at the time were not designed to accept aluminium wire. The first Audi of the modern era was the Audi 100 of 1968. Because of its high conductivity and relatively low price compared to copper at the time, aluminium was introduced for household electrical wiring to a large degree in the United States in the 1960s. However, Volkswagen took the K70 for its own range, spelling the end of NSU as a separate brand.

If the misalignment is not too severe, once cooled they can be bent back into alignment with no negative consequences; of course, if the frame is properly designed for rigidity (see above), this will require enormous force. The mid-sized car that NSU had been working on, the K70, was intended to slot between the rear-engined Prinz models and the futuristic Ro 80. Stresses from overheating aluminium can be relieved by heat-treating the parts in an oven and gradually cooling, in effect annealing the stresses; this can also result, however, in the part becoming distorted as a result of these stresses, so that such heat-treating of welded bicycle frames, for instance, results in a significant fraction becoming misaligned. Presently several lines of Audi cars are produced in Neckarsulm. For this reason, many uses of aluminium in the aerospace industry avoid heat altogether by joining parts using adhesives; this was also used for some of the early aluminium bicycle frames in the 1970s, with unfortunate results when the aluminium tubing corroded slightly, loosening the bond of the adhesive and leading to failure of the frame. In 1967, the new NSU Ro 80 was a space-age car well ahead of its time in technical details such as aerodynamics, light weight, safety, et cetera, but teething problems with the rotary engines put an end to the independence of NSU. Aluminium also will accumulate internal stresses and strains under conditions of overheating; while not immediately obvious, the tendency of the metal to "creep" under sustained stresses results in delayed distortions, for instance the commonly observed warping or cracking of aluminium automobile cylinder heads after an engine is overheated, sometimes as long as years later, or the tendency of welded aluminium bicycle frames to gradually twist out of alignment from the stresses accumulated during the welding process. NSU then focused on new rotary engines according to the ideas of Felix Wankel.

Forming operations where a blow torch is used therefore requires some expertise since no visual signs reveal how close the material is to melting. In the 1950s NSU had been the world's largest manufacturer of motorcycles but had moved on to produce small cars like the NSU Prinz (the TT and TTS versions are still popular as vintage race cars). Even a relatively routine workshop procedure involving heating is complicated by the fact that aluminium, as opposed to steels, will melt without first turning red. In 1969, Audi merged with NSU, based in Neckarsulm near Stuttgart. Often, aluminium's sensitivity to heat must also be considered. Today, aircooled powerplants once produced by VW are no longer placed into production vehicles since December 23, 2005. Even the aluminium cylinder heads and crankcase of the Corvair, built as recently as the 1960s, earned a reputation for failure and stripping of threads in holes, even as large as spark plug holes, which is not seen in current aluminium cylinder heads. Daimler-Benz sold the company to Volkswagen in 1964; subsequently, Volkswagen's purchase of Auto Union has led to the modernization of VW to which it gained expertise in manufacturing water-cooled vehicles.

An Audi engineer commented about the V12 engine, producing over 500 horsepower (370 kW), of an Auto Union race car of the 1930s which was recently restored by the Audi factory, that the aluminium alloy of which the engine was constructed would today be used only for lawn furniture and the like. This model appeared in September 1965, "relaunching" the Audi brand. Similarly, use of aluminium in automotive applications, particularly in engine parts which must survive in difficult conditions, has benefited from development over time. Daimler-Benz developed a 72 hp (54 kW) four-door sedan, with a modern four stroke engine driving the front wheels. For instance, a high frequency of failure in many early aluminium bicycle frames in the 1970s resulted in just such a poor reputation; with a moment's reflection, however, the widespread use of aluminium components in the aerospace and automotive high performance industries, where huge stresses are undergone with vanishingly small failure rates, proves that properly built aluminium bicycle components should not be unusually unreliable, and this has subsequently proved to be the case. In 1958, Daimler-Benz acquired 88 per cent of Auto Union and the next year became its sole owner. The strength and durability of aluminium varies widely, not only as a result of the components of the specific alloy, but also as a result of the particular manufacturing process; for this reason, it has from time to time gained a bad reputation. The company focused efforts on the DKW brand, but their two-stroke engines became unpopular.

Similarly, aluminium bicycle frames can be optimally designed so as to provide rigidity where required, yet have flexibility in terms of absorbing the shock of bumps from the road and not transmitting them to the rider. In that period, the four interlinked rings were used together with the DKW badge. The aluminium chassis members and suspension parts of these cars have large overall dimensions for stiffness but are lightened by reducing cross-sectional area and removing unneeded metal; as a result, they are not only equally or more durable and stiff as the usual steel parts, but they possess an airy gracefulness which most people find attractive. After the war, Zwickau soon became part of the German Democratic Republic and Audi headquarters were moved to Ingolstadt. The latest models of the Corvette automobile, among others, are a good example of redesigning parts to make best use of aluminium's advantages. Auto Union plants were heavily bombed and partly destroyed during World War II. The limit to this process is the increase in susceptibility to what is termed "buckling" failure, where the deviation of the force from any direction other than directly along the axis of the tubing causes folding of the walls of the tubing. The technological development became more and more concentrated and some Audi models were propelled by Horch or Wanderer built engines.

In this way, rigidity can be restored or even enhanced without increasing weight. This badge was used, however, only on Auto Union racing cars in that period while the member companies used their own names and emblems. Aluminium can best be used by redesigning the part to suit its characteristics; for instance making a bicycle of aluminium tubing which has an oversize diameter rather than thicker walls. Before World War II, Auto Union used the four interlinked rings that make up the Audi badge today, representing these four brands. To increase the rigidity by increasing the thickness of the walls of the tubing increases the weight proportionately, so that the advantages of lighter weight are lost as the rigidity is restored. In 1932 Audi merged with Horch, DKW and Wanderer to form the Auto Union. Where failure is not an issue but excessive flex is undesirable due to requirements for precision of location or efficiency of transmission of power, simple replacement of steel tubing with similarly sized aluminium tubing will result in a degree of flex which is undesirable; for instance, the increased flex under operating loads caused by replacing steel bicycle frame tubing with aluminium tubing of identical dimensions will cause misalignment of the power-train as well as absorbing the operating force. Audi cars of that era were luxurious cars equipped with special bodywork.

Therefore, although direct replacement of an iron or steel part with a duplicate made from aluminium may still give acceptable strength to withstand peak loads, the increased flexibility will cause three times more deflection in the part. At the same time, six cylinder and a small four cylinder (licensed from Peugeot) models were manufactured. The reduction by two thirds of the weight of an aluminium part compared to a similarly sized iron or steel part seems enormously attractive, but it should be noted that it is accompanied by a reduction by two thirds in the stiffness of the part. These engines were used in Audi Zwickau and Audi Dresden models that were launched in 1929. Improper use of aluminium can result in problems, particularly in contrast to iron or steel, which appear "better behaved" to the intuitive designer, mechanic, or technician. In 1928, the company was acquired by J S Rasmussen, owner of DKW, who bought the same year the remains of the US automobile manufacturer, Rickenbacker including the manufacturing equipment for eight cylinder engines. [1]. The first six cylinder model (4655 cc) appeared in 1924.

A brief historical overview of alloys and manufacturing technologies is given in Ref. August Horch left the Audi company in 1920. Selecting the right alloy for a given application entails considerations of strength, ductility, formability, weldability and corrosion resistance to name a few. These cars were successful even in sporting events. Alloy systems are classified by a number system (ANSI) or by names indicating their main alloying constituents (DIN and ISO). Audi started with a 2612 cc model followed by a four cylinder model with 3564 cc, as well as 4680 cc and 5720 cc models. Aluminium alloys with a wide range of properties are used in engineering structures. Audi has another production plant in Neckarsulm.

Aluminium is also a superconductor, with a superconducting critical temperature of 1.2 kelvins. Audi produces over 2 million vehicles annually at its main production site in Ingolstadt. Aluminium oxidises very energetically and as a result has found use in solid rocket fuels, thermite, and other pyrotechnic compositions. It is also popularly believed that Audi is an acronym which stands for "Auto Union Deutschland Ingolstadt". Synthetic ruby and sapphire are used in lasers for the production of coherent light. As the word "horch!" translates to "listen!" in German, August Horch settled on the Latin equivalent of his name - "audi!". Aluminium oxide, alumina, is found naturally as corundum (rubies and sapphires), emery, and is used in glass making. August Horch was forced to refrain from using his own family name in his new car business.

Some of the many uses for aluminium are in:. His former partners sued him for trademark infringement and a German court determined that the Horch brand belonged to his former company.
. He then started a new company in Zwickau and continued using the Horch brand. Telescope mirrors are also coated with a thin layer of aluminium, but are front coated to avoid internal reflections even though this makes the surface more susceptible to damage. In 1910, Horch was forced out of the company he had founded. In particular, nearly all modern mirrors are made using a thin reflective coating of aluminium on the back surface of a sheet of float glass. The first Horch automobile was produced in 1901 in Zwickau, in former East Germany.

These coatings form a thin layer of protective aluminium oxide that does not deteriorate as silver coatings do. The company traces its origins back to 1899 and August Horch. When aluminium is evaporated in a vacuum it forms a coating that reflects both visible light and infrared. . Aluminium alloys form vital components of aircraft and rockets as a result of their high strength to weight ratio. The tagline is used either in original or in its English translation "Advantage through Technology". When combined with thermo-mechanical processing aluminium alloys display a marked improvement in mechanical properties. Audi's German tagline is "Vorsprung durch Technik".

Conversely, the term "alloy" in general use today usually means aluminium alloy. The company is headquartered in Ingolstadt, Bavaria, Germany. Pure aluminium is encountered only when corrosion resistance is more important than strength or hardness. Audi is an automobile maker in Germany, and is a wholly-owned subsidiary of the Volkswagen Group. Today almost all materials that claim to be aluminium are actually an alloy thereof. Audi Roadjet. Pure aluminium has a low tensile strength, but readily forms alloys with many elements such as copper, zinc, magnesium, manganese and silicon (e.g.duralumin). Audi Le Mans Quattro.

Whether measured in terms of quantity or value, the use of aluminium exceeds that of any other metal except iron, and it is important in virtually all segments of the world economy. Audi Nuvolari Quattro. It is the second most malleable metal (after gold) and the sixth most ductile. Audi Pikes Peak. Aluminium mirror finish has the highest reflectance of any metal in the 200-400 nm (UV) , and the 3000-10000 nm (far IR) regions, while in the 400-700 nm visible range it is slightly outdone by silver, and in the 700-3000 (near IR) by silver, gold and copper. Audi Avantissimo. Aluminium is about one-third as dense as steel or copper; is malleable, ductile, and easily machined and cast; and has excellent corrosion resistance and durability due to the protective oxide layer. Audi Quattro Spyder.

Pure aluminium has a tensile strength of about 49 megapascals (MPa) and 700 MPa if it is formed into an alloy. Audi Avus Quattro. Aluminium is nontoxic (as the metal), non-magnetic, and non-sparking. Audi Shooting Brake, design study for the next generation TT. Aluminium is a soft and lightweight metal with a dull silvery appearance, due to a thin layer of oxidation that forms quickly when it is exposed to air. Audi Allroad Quattro Concept. . Audi RSQ designed exclusively for the 2004 film I, Robot.

Structural components made from aluminium and its alloys are vital to the aerospace industry and very important in other areas of transportation and building in which light weight, durability, and strength are needed. R8. Aluminium is used in many industries to make millions of different products and is very important to the world economy. Q5. Aluminium is found primarily as the ore bauxite and is remarkable for its resistance to oxidation (due to the phenomenon of passivation) and its light weight. RS4. It is a silvery and ductile member of the poor metal group of chemical elements. A5.

Aluminium or aluminum (see the spelling section below) is the chemical element in the periodic table that has the symbol Al and atomic number 13. model. In the film Star Trek IV: The Voyage Home, Scotty devises the fictional material transparent aluminum. Audi UrS4/S6. The aluminohalides have a similar structure. Audi V8. It has many uses in organic chemistry, particularly as a reducing agent. Audi Quattro.

It decomposes into lithium hydride, aluminium and hydrogen when heated, and is hydrolysed by water. Audi 100/200/5000. Alumino-hydrides of the most electropositive elements are known, the most useful being lithium aluminium hydride, Li[AlH4]. Audi 80/90/4000. They have some uses in organic synthesis, for instance trimethylaluminium. Audi 50. Organo-metallic compounds of empirical formula AlR3 exist and, if not also giant molecules, are at least dimers or trimers. TT.

The other trihalides are dimeric, having a bridge-like structure. S8. It is very inert. A8

    . It consists of a giant molecule which sublimes without melting at 1291 °C. Q7. Aluminium fluoride, AlF3, is made by treating the hydroxide with HF, or can be made from the elements. RS6.

    It is polymorphic. S6. Aluminium sulfide, Al2S3, may be prepared by passing hydrogen sulfide over aluminium powder. A6

      . It exists in various crystalline forms. RS4. It is amphoteric, being both a very weak acid, and forming aluminates with alkalis. S4.

      Aluminium hydroxide may be prepared as a gelatinous precipitate by adding ammonia to an aqueous solution of an aluminium salt. A4

        . It is almost insoluble in water. S3. As a gemstone, its hardness is only exceeded by diamond, boron nitride and carborundum. A3
          . Aluminium oxide, Al2O3, occurs naturally as corundum, and can be made by burning aluminium in oxygen or by heating the hydroxide, nitrate or sulfate. A2.

          Aluminium phosphide, AlP, is made similarly, and hydrolyses to give phosphine. It is hydrolysed by water to form ammonia and aluminium hydroxide. Aluminium nitride, AlN, can be made from the elements at 800 °C. The acetylide, Al2(C2)3, is made by passing acetylene over heated aluminium.

          The pale yellow crystals have a complex lattice structure, and react with water or dilute acids to give methane. Aluminium carbide, Al4C3 is made by heating a mixture of the elements above 1000 °C. It can also be prepared by the action of aluminium chloride on lithium hydride in ether solution, but cannot be isolated free from the solvent. It burns explosively in air.

          Aluminium hydride, (AlH3)n, can be produced from trimethylaluminium and an excess of hydrogen. The salts of strong acids, such as nitrate, are stable and soluble in water, forming hydrates with at least six molecules of water of crystallization. The hydroxide is a weak base and aluminium salts of weak bases, such as carbonate, can't be prepared. Fajans rules show that the simple trivalent cation Al3+ is not expected to be found in anhydrous salts or binary compounds such as Al2O3.

          Aluminium suboxide, AlO can be shown to be present when aluminium powder burns in oxygen. AlF, AlCl and AlBr exist in the gaseous phase when the tri-halide is heated with aluminium. The selenide is made in a parallel manner. It quickly disproportionates to the starting materials.

          Al2S can be made by heating Al2S3 with aluminium shavings at 1300 °C in a vacuum. Al2O is made by heating the normal oxide, Al2O3, with silicon at 1800 °C in a vacuum. AlH is produced when aluminium is heated at 1500 °C in an atmosphere of hydrogen. Galvanic corrosion from the dissimilar metals increases the electrical resistance of the connection.

          Pure aluminium has a tendency to "creep" under steady sustained pressure (to a greater degree as the temperature rises), again producing a degree of looseness in an initially tight connection. The greater coefficient of thermal expansion of aluminium, causes the wire to expand and contract relative to the dissimilar metal screw connection, eventually loosening the connection. Copper heat sinks are smaller although more expensive and harder to manufacture. Most modern computer CPU heat sinks are made of aluminium due to its ease of manufacture and good heat conductivity.

          Anodised aluminium is more stable to further oxidation, and is used in various fields of construction. Aluminium flakes may also be included in undercoat paints, particularly wood primer — on drying, the flakes overlap to produce a water resistant barrier. Powdered aluminium, a commonly used silvering agent in paint. Super purity aluminium (SPA, 99.980% to 99.999% Al), used in electronics and CDs.

          MKM steel and Alnico magnets, although non-magnetic itself. Machinery. Electrical transmission lines (aluminium conductors are half the weight of copper for equal conductivity and lower in price[1]). Consumer durable goods (appliances, cooking utensils, etc.).

          Construction (windows, doors, siding, building wire, etc. Water treatment. Packaging (cans, foil, etc.). Transportation (automobiles, airplanes, trucks, railroad cars, marine vessels, etc.).