This page will contain additional articles about John Dalton, as they become available.John Dalton
John Dalton (September 6, 1766 – July 27, 1844) was a British chemist and physicist, born at Eaglesfield, near Cockermouth in Cumberland. He is most well known for his advocacy of the atomic theory. BiographyEarly lifeDalton received his early education from his father and from John Fletcher, a teacher of the Quaker school at Cumberland, on whose retirement in 1778 he himself started teaching. This youthful venture was not successful, the amount he received in fees being only about five shillings a week, and after two years he took to farm work. But he had received some instruction in mathematics from a distant relative, Elihu Robinson, and in 1781 he left his native village to become assistant to his cousin George Bewley, who kept a school at Kendal. There he passed the next twelve years, becoming in 1785, through the retirement of his cousin, joint manager of the school with his elder brother Jonathan. About 1790 he seems to have thought of taking up law or medicine, but his projects met with no encouragement from his relatives and he remained at Kendal until, in the spring of 1793, he moved to Manchester. Mainly through John Gough, a blind philosopher to whose aid he owed much of his scientific knowledge, he was appointed teacher of mathematics and natural philosophy at the Manchester Academy. He remained in that position until the relocation of the college to York in 1803, when he became a public and private teacher of mathematics and chemistry. Among his pupils were: Eaton Hodgkinson and James Prescott Joule. Meteorology, vision and miscellanyDuring his years in Kendal, Dalton had contributed solutions of problems and questions on various subjects to the Gentlemen's and Ladies' Diaries, and in 1787 he began to keep a meteorological diary in which, during the succeeding fifteen years, he entered more than 200,000 observations. His first separate publication was Meteorological Observations and Essays (1793), which contained the germs of several of his later discoveries. However, in spite of the originality of his treatment, the book met with only a limited sale. Another work by him, Elements of English Grammar, was published in 1801. In 1794 he was elected a member of the Manchester Literary and Philosophical Society, the Lit & Phil, and a few weeks after election he communicated his first paper on Extraordinary facts relating to the vision of colours, in which he gave the earliest account of the optical peculiarity known as Daltonism or colour blindness, and summed up its characteristics as observed in himself and others, including his brother. Besides the blue and purple of the spectrum he was able to recognize only one colour, yellow, or, as he says in his paper, that part of the image which others call red appears to me little more than a shade or defect of light. After that the orange, yellow and green seem one colour which descends pretty uniformly from an intense to a rare yellow, making what I should call different shades of yellow. This paper was followed by many others on diverse topics on rain and dew and the origin of springs, on heat, the colour of the sky, steam, the auxiliary verbs and participles of the English language and the reflection and refraction of light. Atomic theoryIn 1800 he became a secretary of the Lit & Phil, and in the following year he presented the important paper or series of papers, entitled Experimental Essays on the constitution of mixed gases; on the pressure of steam and other vapours at different temperatures, both in a vacuum and in air; on evaporation; and on the thermal expansion of gases. The second of these essays opens with the striking remark,
After describing experiments to ascertain the pressure of steam at various points between 0 ° and 100°C (32° and 212°F), he concluded from observations on the vapour pressure of six different liquids, that the variation of vapour pressure for all liquids is equivalent, for the same variation of temperature, reckoning from vapour of any given pressure. In the fourth essay he remarks,
He thus enunciated Gay-Lussac's law, stated some months later by Joseph Louis Gay-Lussac. In the two or three years following the reading of these essays, he published several papers on similar topics, that on the absorption of gases by water and other liquids (1803), containing his law of partial pressures. The most important of all Dalton's investigations are those concerned with the atomic theory in chemistry, with which his name is inseparably associated. It has been proposed that this theory was suggested to him either by researches on ethylene (olefiant gas) and methane (carburetted hydrogen) or by analysis of nitrous oxide (protoxide of azote) and nitrogen dioxide (deutoxide of azote), both views resting on the authority of Thomas Thomson. However, a study of Dalton's own laboratory notebooks, discovered in the rooms of the Lit & Phil[1], concluded that so far from Dalton being led to the idea, that chemical combination consists in the interaction of atoms of definite and characteristic weight, by his search for an explanation of the law of multiple proportions, the idea of atomic structure arose in his mind as a purely physical concept, forced upon him by study of the physical properties of the atmosphere and other gases. The first published indications of this idea are to be found at the end of his paper on the absorption of gases already mentioned, which was read on October 21, 1803 though not published till 1805. Here he says:
He proceeds to give what has been quoted as his first table of atomic weights, but in his laboratory notebooks[2] there is an earlier one dated 1803 in which he sets out the relative weights of the atoms of a number of substances, derived from analysis of water, ammonia, carbon dioxide, etc. by chemists of the time. It appears, then, that confronted with the problem of calculating the relative diameter of the atoms of which, he was convinced, all gases were made, he used the results of chemical analysis. Assisted by the assumption that combination always takes place in the simplest possible way, he thus arrived at the idea that chemical combination takes place between particles of different weights, and this it was which differentiated his theory from the historic speculations of the Greeks. The extension of this idea to substances in general necessarily led him to the law of multiple proportions, and the comparison with experiment brilliantly confirmed his deduction[3]. It may be noted that in a paper on the proportion of the gases or elastic fluids constituting the atmosphere, read by him in November 1802, the law of multiple proportions appears to be anticipated in the words: The elements of oxygen may combine with a certain portion of nitrous gas or with twice that portion, but with no intermediate quantity, but there is reason to suspect that this sentence was added some time after the reading of the paper, which was not published till 1805. Many of Dalton's ideas were acquired from other chemists at the time, such as Antoine Lavoisier and William Higgins. However, he was the first to put the ideas into a universal atomic theory, which was undoubtedly his greatest achievement. Later yearsDalton communicated his atomic theory to Thomson who, by consent, included an outline of it in the third edition of his System of Chemistry (1807), and Dalton gave a further account of it in the first part of the first volume of his New System of Chemical Philosophy (1808). The second part of this volume appeared in 1810, but the first part of the second volume was not issued till 1827, though the printing of it began in 1817. This delay is not explained by any excess of care in preparation, for much of the matter was out of date and the appendix giving the author's latest views is the only portion of special interest. The second part of vol. ii. never appeared. Dalton was president of the Lit & Phil from 1817 until his death, contributing 116 memoirs. Of these the earlier are the most important. In one of them, read in 1814, he explains the principles of volumetric analysis, in which he was one of the earliest workers. In 1840 a paper on the phosphates and arsenates, often regarded as a weaker work, was refused by the Royal Society, and he was so incensed that he published it himself. He took the same course soon afterwards with four other papers, two of which On the quantity of acids, bases and salts in different varieties of salts and On a new and easy method of analysing sugar, contain his discovery, regarded by him as second in importance only to the atomic theory, that certain anhydrates, when dissolved in water, cause no increase in its volume, his inference being that the salt enters into the pores of the water. Dalton's experimental methodAs an investigator, Dalton was content with rough and inaccurate instruments, though better ones were readily attainable. Sir Humphry Davy described him as a very coarse experimenter, who almost always found the results he required, trusting to his head rather than his hands. In the preface to the second part of vol. i. of his New System he says he had so often been misled by taking for granted the results of others that he determined to write as little as possible but what I can attest by my own experience, but this independence he carried so far that it sometimes resembled lack of receptivity. Thus he distrusted, and probably never fully accepted, Gay-Lussac's conclusions as to the combining volumes of gases. He held peculiar and quite unfounded views about chlorine. Even after its elementary character had been settled by Davy, he persisted in using the atomic weights he himself had adopted, even when they had been superseded by the more accurate determinations of other chemists. He always objected to the chemical notation devised by Jöns Jakob Berzelius, although by common consent it was much simpler and more convenient than his own cumbersome system of circular symbols. His library, he was once heard to declare, he could carry on his back, yet reputedly he had not read half the books it contained. Public lifeBefore he had propounded the atomic theory he had already attained a considerable scientific reputation. In 1804 he was chosen to give a course of lectures on natural philosophy at the Royal Institution in London, where he delivered another course in 1809–1810. However, he was deficient, it would seem, in the qualities that make an attractive lecturer, being harsh and indistinct in voice, ineffective in the treatment of his subject, and singularly wanting in the language and power of illustration. In 1810 he was asked by Davy to offer himself as a candidate for the fellowship of the Royal Society, but declined, possibly for financial reasons. However, in 1822 he was proposed without his knowledge, and on election paid the usual fee. Six years previously he had been made a corresponding member of the French Académie des Sciences, and in 1830 he was elected as one of its eight foreign associates in place of Davy. In 1833 Lord Grey's government conferred on him a pension of £150, raised in 1836 to £300. Dalton never married, though there is evidence that he enjoyed the company of educated and refined women. He lived for more than a quarter of a century with his friend the Rev. W. Johns (1771–1845), in George Street, Manchester, where his daily round of laboratory work and tuition was broken only by annual excursions to the Lake District and occasional visits to London. In 1822 he paid a short visit to Paris, where he met many distinguished resident scientists. He attended several of the earlier meetings of the British Association at York, Oxford, Dublin and Bristol. Death and legacyDalton died in Manchester in 1844 of paralysis. He had suffered a first attack in 1837, and a second in 1838 had left him enfeebled, both physically and mentally, though he remained able to make experiments. In May 1844 he had another stroke and on July 26 he recorded with trembling hand his last meteorological observation. On the 27th he fell from his bed and was found lifeless by his attendant. A bust of him, by Francis Legatt Chantrey, was publicly subscribed for him and placed in the entrance hall of the Royal Manchester Institution. It now stands in the entrance to Manchester Town Hall. Dalton had requested that his eyes be examined after his death, in an attempt to discover the cause of his colour-blindness. He had hypothesised that his aqueous humour might be coloured blue. Post-mortem examination showed that the humours of the eye were perfectly normal. However, an eye was preserved at the Royal Institution, and a 1990s study on DNA extracted from the eye showed that he had lacked the pigment that gives sensitivity to the colour green, the classic condition known as a deuteranope. In honour of his work with ratios and chemicals that led to the idea of atoms and atomic weights, many chemists and biochemists use the (still unofficial) unit dalton (abbreviated Da) to denote one atomic mass unit, or 1/12 the weight of a neutral atom of carbon-12.
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In honour of his work with ratios and chemicals that led to the idea of atoms and atomic weights, many chemists and biochemists use the (still unofficial) unit dalton (abbreviated Da) to denote one atomic mass unit, or 1/12 the weight of a neutral atom of carbon-12. Element 96 Curium (Cm) was named in her and Pierre's honour. However, an eye was preserved at the Royal Institution, and a 1990s study on DNA extracted from the eye showed that he had lacked the pigment that gives sensitivity to the colour green, the classic condition known as a deuteranope. Her picture also appeared on the French 500 franc note and on stamps and coins. Post-mortem examination showed that the humours of the eye were perfectly normal. Curie's picture was on the Polish inflationary late-1980s 20,000-zloty banknote. He had hypothesised that his aqueous humour might be coloured blue. An extremely ahistorical Marie Curie appears as a character in the comedy Young Einstein by Yahoo Serious. Dalton had requested that his eyes be examined after his death, in an attempt to discover the cause of his colour-blindness. Oscar-nominated film based on it. It now stands in the entrance to Manchester Town Hall. S. A bust of him, by Francis Legatt Chantrey, was publicly subscribed for him and placed in the entrance hall of the Royal Manchester Institution. There is a 1943 U. On the 27th he fell from his bed and was found lifeless by his attendant. In 1995, Madame Curie was the first woman laid to rest under the famous dome of The Panthéon in Paris on her own merits. In May 1844 he had another stroke and on July 26 he recorded with trembling hand his last meteorological observation. Her younger daughter, Eve Curie, wrote her biography Madame Curie after her death. He had suffered a first attack in 1837, and a second in 1838 had left him enfeebled, both physically and mentally, though he remained able to make experiments. Her elder daughter, Irène Joliot-Curie, won a Nobel Prize for Chemistry in 1935, the year after Marie Curie's death. Dalton died in Manchester in 1844 of paralysis. Her death near Sallanches, France in 1934 was from leukemia, almost certainly due to her massive exposure to radiation in her work. He attended several of the earlier meetings of the British Association at York, Oxford, Dublin and Bristol. In her later years, she was disappointed by the myriad of physicians and makers of cosmetics who used radioactive material without precautions. In 1822 he paid a short visit to Paris, where he met many distinguished resident scientists. In 1921, she did a tour of the United States, where she was welcomed triumphantly, to raise funds for research on radium. Johns (1771–1845), in George Street, Manchester, where his daily round of laboratory work and tuition was broken only by annual excursions to the Lake District and occasional visits to London. Promptly after the war started, she cashed in her and her husband's gold Nobel Prize Medals for the war effort. W. Marie personally provided the tubes, milked from the radium she purified. He lived for more than a quarter of a century with his friend the Rev. These units were powered using tubes of radium emanation, a colorless, radioactive gas given off by radium, later to be identified as radon. Dalton never married, though there is evidence that he enjoyed the company of educated and refined women. During World War I, she pushed for the use of mobile radiography units for the treatment of wounded soldiers. In 1833 Lord Grey's government conferred on him a pension of £150, raised in 1836 to £300. It is a strange coincidence that Paul Langevin's grandson Michel later married her granddaughter Hélène Langevin-Joliot. Six years previously he had been made a corresponding member of the French Académie des Sciences, and in 1830 he was elected as one of its eight foreign associates in place of Davy. France at the time was still reeling from the effects of the Dreyfus affair, so the scandal's effect on the public was all the more acute. However, in 1822 he was proposed without his knowledge, and on election paid the usual fee. Despite her fame as an honored scientist working for France, the public's attitude to the scandal tended towards xenophobia—she was a foreigner, from an unknown land (Poland was still referred to as a geographical area, under the Russian Tsar), an area known to have a significant Jewish population (Marie was an atheist, raised a Catholic, but that didn't seem to matter). In 1810 he was asked by Davy to offer himself as a candidate for the fellowship of the Royal Society, but declined, possibly for financial reasons. After her husband's death, she supposedly had an affair with physicist Paul Langevin, a married man who had left his wife, which resulted in a press scandal, invented by her academic opponents to smear her credibility. However, he was deficient, it would seem, in the qualities that make an attractive lecturer, being harsh and indistinct in voice, ineffective in the treatment of his subject, and singularly wanting in the language and power of illustration. She is one of only two people who has been awarded a Nobel Prize in two different fields, the other being Linus Pauling. In 1804 he was chosen to give a course of lectures on natural philosophy at the Royal Institution in London, where he delivered another course in 1809–1810. She was the first person to win or share two Nobel Prizes. Before he had propounded the atomic theory he had already attained a considerable scientific reputation. In an unusual move, Curie intentionally did not patent the radium isolation process, instead leaving it open so the scientific community could research unhindered. His library, he was once heard to declare, he could carry on his back, yet reputedly he had not read half the books it contained. Eight years later, she received the Nobel Prize in Chemistry, 1911 "in recognition of her services to the advancement of chemistry by the discovery of the elements radium and polonium, by the isolation of radium and the study of the nature and compounds of this remarkable element". He always objected to the chemical notation devised by Jöns Jakob Berzelius, although by common consent it was much simpler and more convenient than his own cumbersome system of circular symbols. She was the first woman to be awarded a Nobel Prize. Even after its elementary character had been settled by Davy, he persisted in using the atomic weights he himself had adopted, even when they had been superseded by the more accurate determinations of other chemists. Together with Pierre Curie and Henri Becquerel, she was awarded the Nobel Prize in Physics, 1903: "in recognition of the extraordinary services they have rendered by their joint researches on the radiation phenomena discovered by Professor Henri Becquerel". He held peculiar and quite unfounded views about chlorine. The first they named polonium after Marie's native country, and the other was named radium from its intense radioactivity. Thus he distrusted, and probably never fully accepted, Gay-Lussac's conclusions as to the combining volumes of gases. Over several years of unceasing labour they refined several tons of pitchblende, progressively concentrating the radioactive components, and eventually isolated initially the chloride salts (refining radium chloride on April 20, 1902) and then two new chemical elements. of his New System he says he had so often been misled by taking for granted the results of others that he determined to write as little as possible but what I can attest by my own experience, but this independence he carried so far that it sometimes resembled lack of receptivity. By 1898 they deduced a logical explanation: that the pitchblende contained traces of some unknown radioactive component which was far more radioactive than uranium; thus on December 26th Marie Curie announced the existence of this new substance. i. Together they studied radioactive materials, particularly the uranium ore pitchblende, which had the curious property of being more radioactive than the uranium extracted from it. In the preface to the second part of vol. At the Sorbonne she met and married another instructor, Pierre Curie. Sir Humphry Davy described him as a very coarse experimenter, who almost always found the results he required, trusting to his head rather than his hands. Eventually, with the monetary assistance of her elder sister, she moved to Paris and studied chemistry and physics at the Sorbonne, where she became the first woman to teach. As an investigator, Dalton was content with rough and inaccurate instruments, though better ones were readily attainable. Due to her gender, she was not allowed admission into any Russian or Polish universities so she worked as a governess for several years. He took the same course soon afterwards with four other papers, two of which On the quantity of acids, bases and salts in different varieties of salts and On a new and easy method of analysing sugar, contain his discovery, regarded by him as second in importance only to the atomic theory, that certain anhydrates, when dissolved in water, cause no increase in its volume, his inference being that the salt enters into the pores of the water. After graduating from high school, she suffered a mental breakdown for a year. In 1840 a paper on the phosphates and arsenates, often regarded as a weaker work, was refused by the Royal Society, and he was so incensed that he published it himself. She was notable for her diligent work ethic, neglecting even food and sleep to study. In one of them, read in 1814, he explains the principles of volumetric analysis, in which he was one of the earliest workers. Born in Warsaw, Poland, her first years were sorrowful ones, marked by the death of her sister and, four years later, her mother. Of these the earlier are the most important. . Dalton was president of the Lit & Phil from 1817 until his death, contributing 116 memoirs. She founded the Curie Institutes in Paris and in Warsaw. never appeared. Marie Curie (Maria Skłodowska-Curie, November 7, 1867 – July 4, 1934), (Dolega coat of arms) was a Polish-born French chemist and pioneer in the early field of radiology and a two-time Nobel laureate. ii. Obsessive Genius: The Inner World of Marie Curie, by Barbara Goldsmith, ISBN 0393051374. The second part of vol. Marie Curie: A Life, by Susan Quinn, ISBN 0201887940. This delay is not explained by any excess of care in preparation, for much of the matter was out of date and the appendix giving the author's latest views is the only portion of special interest. Madame Curie: A Biography, by Eve Curie, ISBN 0306810387. The second part of this volume appeared in 1810, but the first part of the second volume was not issued till 1827, though the printing of it began in 1817. Dalton communicated his atomic theory to Thomson who, by consent, included an outline of it in the third edition of his System of Chemistry (1807), and Dalton gave a further account of it in the first part of the first volume of his New System of Chemical Philosophy (1808). However, he was the first to put the ideas into a universal atomic theory, which was undoubtedly his greatest achievement. Many of Dalton's ideas were acquired from other chemists at the time, such as Antoine Lavoisier and William Higgins. It may be noted that in a paper on the proportion of the gases or elastic fluids constituting the atmosphere, read by him in November 1802, the law of multiple proportions appears to be anticipated in the words: The elements of oxygen may combine with a certain portion of nitrous gas or with twice that portion, but with no intermediate quantity, but there is reason to suspect that this sentence was added some time after the reading of the paper, which was not published till 1805. The extension of this idea to substances in general necessarily led him to the law of multiple proportions, and the comparison with experiment brilliantly confirmed his deduction[3]. Assisted by the assumption that combination always takes place in the simplest possible way, he thus arrived at the idea that chemical combination takes place between particles of different weights, and this it was which differentiated his theory from the historic speculations of the Greeks. It appears, then, that confronted with the problem of calculating the relative diameter of the atoms of which, he was convinced, all gases were made, he used the results of chemical analysis. by chemists of the time. He proceeds to give what has been quoted as his first table of atomic weights, but in his laboratory notebooks[2] there is an earlier one dated 1803 in which he sets out the relative weights of the atoms of a number of substances, derived from analysis of water, ammonia, carbon dioxide, etc. Here he says:. The first published indications of this idea are to be found at the end of his paper on the absorption of gases already mentioned, which was read on October 21, 1803 though not published till 1805. However, a study of Dalton's own laboratory notebooks, discovered in the rooms of the Lit & Phil[1], concluded that so far from Dalton being led to the idea, that chemical combination consists in the interaction of atoms of definite and characteristic weight, by his search for an explanation of the law of multiple proportions, the idea of atomic structure arose in his mind as a purely physical concept, forced upon him by study of the physical properties of the atmosphere and other gases. It has been proposed that this theory was suggested to him either by researches on ethylene (olefiant gas) and methane (carburetted hydrogen) or by analysis of nitrous oxide (protoxide of azote) and nitrogen dioxide (deutoxide of azote), both views resting on the authority of Thomas Thomson. The most important of all Dalton's investigations are those concerned with the atomic theory in chemistry, with which his name is inseparably associated. In the two or three years following the reading of these essays, he published several papers on similar topics, that on the absorption of gases by water and other liquids (1803), containing his law of partial pressures. He thus enunciated Gay-Lussac's law, stated some months later by Joseph Louis Gay-Lussac. In the fourth essay he remarks,. After describing experiments to ascertain the pressure of steam at various points between 0 ° and 100°C (32° and 212°F), he concluded from observations on the vapour pressure of six different liquids, that the variation of vapour pressure for all liquids is equivalent, for the same variation of temperature, reckoning from vapour of any given pressure. The second of these essays opens with the striking remark,. In 1800 he became a secretary of the Lit & Phil, and in the following year he presented the important paper or series of papers, entitled Experimental Essays on the constitution of mixed gases; on the pressure of steam and other vapours at different temperatures, both in a vacuum and in air; on evaporation; and on the thermal expansion of gases. This paper was followed by many others on diverse topics on rain and dew and the origin of springs, on heat, the colour of the sky, steam, the auxiliary verbs and participles of the English language and the reflection and refraction of light. After that the orange, yellow and green seem one colour which descends pretty uniformly from an intense to a rare yellow, making what I should call different shades of yellow. Besides the blue and purple of the spectrum he was able to recognize only one colour, yellow, or, as he says in his paper, that part of the image which others call red appears to me little more than a shade or defect of light. In 1794 he was elected a member of the Manchester Literary and Philosophical Society, the Lit & Phil, and a few weeks after election he communicated his first paper on Extraordinary facts relating to the vision of colours, in which he gave the earliest account of the optical peculiarity known as Daltonism or colour blindness, and summed up its characteristics as observed in himself and others, including his brother. Another work by him, Elements of English Grammar, was published in 1801. However, in spite of the originality of his treatment, the book met with only a limited sale. His first separate publication was Meteorological Observations and Essays (1793), which contained the germs of several of his later discoveries. During his years in Kendal, Dalton had contributed solutions of problems and questions on various subjects to the Gentlemen's and Ladies' Diaries, and in 1787 he began to keep a meteorological diary in which, during the succeeding fifteen years, he entered more than 200,000 observations. Among his pupils were: Eaton Hodgkinson and James Prescott Joule. He remained in that position until the relocation of the college to York in 1803, when he became a public and private teacher of mathematics and chemistry. Mainly through John Gough, a blind philosopher to whose aid he owed much of his scientific knowledge, he was appointed teacher of mathematics and natural philosophy at the Manchester Academy. About 1790 he seems to have thought of taking up law or medicine, but his projects met with no encouragement from his relatives and he remained at Kendal until, in the spring of 1793, he moved to Manchester. There he passed the next twelve years, becoming in 1785, through the retirement of his cousin, joint manager of the school with his elder brother Jonathan. But he had received some instruction in mathematics from a distant relative, Elihu Robinson, and in 1781 he left his native village to become assistant to his cousin George Bewley, who kept a school at Kendal. This youthful venture was not successful, the amount he received in fees being only about five shillings a week, and after two years he took to farm work. Dalton received his early education from his father and from John Fletcher, a teacher of the Quaker school at Cumberland, on whose retirement in 1778 he himself started teaching. . He is most well known for his advocacy of the atomic theory. John Dalton (September 6, 1766 – July 27, 1844) was a British chemist and physicist, born at Eaglesfield, near Cockermouth in Cumberland. DM Hunt, KS Dulai, JK Bowmaker, JD Mollon, "The chemistry of John Dalton's color blindness." Science Feb 17 1995. Roscoe and Harden, A New View of the Origin of Dalton's Atomic Theory (1896). Angus Smith, Memoir of John Dalton and History of the Atomic Theory. Henry, Life of Dalton, Cavendish Society (1854). ^ Roscoe & Harden (1896), pp. 50,51. ^ Laboratory notebooks for 1802–1804, under the date 6th September 1803, on p.248. ^ Roscoe & Harden (1896). |